(-)-DIPIVALOYL-L-TARTARIC ACID

(-)-DIPIVALOYL-L-TARTARIC ACID Basic information
Product Name:(-)-DIPIVALOYL-L-TARTARIC ACID
Synonyms:Butanedioic acid,2,3-bis(2,2-diMethyl-1-oxopropoxy)-, (2R,3R)-;(2R,3R)-2,3-Bis(2,2-dimethyl-1-oxopropoxy)butanedioic acid;L-Dipivaloyltartaric acid;(2R,3R)-2,3-Bis(pivaloyloxy)succinic acid;(-)-BIS(2,2-DIMETHYLPROPIONYL)-L-TARTARIC ACID;(-)-DIPIVALOYL-L-TARTARIC ACID;DIPIVALOYL-L-TARTARIC ACID;(-)-DI-O,O'-PIVALOYL-L-TARTARIC ACID
CAS:65259-81-6
MF:C14H22O8
MW:318.32
EINECS:
Product Categories:chiral;Asymmetric Synthesis;Synthetic Organic Chemistry
Mol File:65259-81-6.mol
(-)-DIPIVALOYL-L-TARTARIC ACID Structure
(-)-DIPIVALOYL-L-TARTARIC ACID Chemical Properties
Melting point 127-132 °C
Boiling point 436.6±45.0 °C(Predicted)
density 1.240±0.06 g/cm3(Predicted)
refractive index -24 ° (C=2, Dioxane)
storage temp. Inert atmosphere,Room Temperature
pka1.68±0.25(Predicted)
form powder to crystal
color White to Almost white
optical activity[α]20/D 23.5±1°, c = 1.7% in dioxane
Sensitive Hygroscopic
BRN 2008171
CAS DataBase Reference65259-81-6(CAS DataBase Reference)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 29189900
MSDS Information
ProviderLanguage
SigmaAldrich English
(-)-DIPIVALOYL-L-TARTARIC ACID Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses(?)-O,O′-Di-pivaloyl-L-tartaric acid can be used:
  • As a chiral staple in the synthesis of helical π-conjugated cyclic nanocoils, which are used as nano springs, nano solenoids, and pressure sensors.
  • As an additive in the iridium-catalyzed C-H amidation reactions of arylphosphoryl compounds.

(-)-DIPIVALOYL-L-TARTARIC ACID Preparation Products And Raw materials
Raw materialsPivaloyl chloride-->L(+)-Tartaric acid
(+)-DIPIVALOYL-D-TARTARIC ACID,DIPIVALOYL-D-TARTARIC ACID 2-ISOBUTOXYACETIC ACID DIPIVALOYL-D-TARTARIC ACID,(+)-DIPIVALOYL-D-TARTARIC ACID,O,O`-Dipivaloyl-D-tartaric acid ,DIPIVALOYL-D-TARTARIC ACID 98% (-)-DIACETYL-L-TARTARIC ACID ISOBUTYRIC ACID 2-ETHOXYETHYL ESTER (-)-DIPIVALOYL-L-TARTARIC ACID

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