4-Bromo-3-nitrotoluene

4-Bromo-3-nitrotoluene Basic information
Product Name:4-Bromo-3-nitrotoluene
Synonyms:Benzene, 1-bromo-4-methyl-2-nitro-;4-BROMO-3-NITROTOLUENE;BROMONITROTOLUENE-4;4-BROMO-3-NITROTOLUENE 99%;1-Nitro-2-bromo-5-methylbenzene;4-Bromo-3-nitrotoluene,99%;4-BROMO-3-NITROTOLUENE, TECH., 90%;3-nitro-4-broMotoluol
CAS:5326-34-1
MF:C7H6BrNO2
MW:216.03
EINECS:226-203-6
Product Categories:Aromatic Hydrocarbons (substituted) & Derivatives;Halogen toluene;Bromine Compounds;Nitro Compounds;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks
Mol File:5326-34-1.mol
4-Bromo-3-nitrotoluene Structure
4-Bromo-3-nitrotoluene Chemical Properties
Melting point 31-33 °C (lit.)
Boiling point 151.5-152.5 °C/14 mmHg (lit.)
density 1.578 g/mL at 25 °C (lit.)
refractive index 1.5930 (estimate)
Fp >230 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
form powder to lump to clear liquid
color White or Colorles to Yellow to Orange
Specific Gravity1.578
FreezingPoint 29.0 to 33.0 ℃
Sensitive Light Sensitive
BRN 1945925
CAS DataBase Reference5326-34-1(CAS DataBase Reference)
NIST Chemistry Reference4-Bromo-3-nitrotoluene(5326-34-1)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-22-20/21/22
Safety Statements 26-36-36/37-36/37/39-22
WGK Germany 3
HazardClass IRRITANT
HS Code 29049090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
4-Bromo-3-nitrotoluene Usage And Synthesis
Chemical PropertiesLow melting solid
Uses4-Bromo-3-nitrotoluene may be used as a starting material in the synthesis of 2-bromo-5-methylaniline and as a reagent in the synthesis of 2-nitro-4:4′-dimethyl-diphenyl by reacting with p-iodotoluene.
General Description4-Bromo-3-nitrotoluene (2-bromo-5-methylnitrobenzene, 1-bromo-4-methyl-2-nitrobenzene) is a halonitrobenzene. It has been synthesized from 4-methyl-2-nitroaniline and confirmed by 1H NMR. The crystal structure of 1-bromo-4-methyl-2-nitrobenzene is found to be orthorhombic in the Pna21 space group. Its enthalpy of vaporization at boiling point has been determined.
4-Bromo-3-nitrotoluene Preparation Products And Raw materials
Raw materials4-Bromo-2-nitrotoluene-->4-METHYL-2-NITROBENZOIC ACID 97-->4'-methyl-2'-nitroacetanilide
Preparation Products2-Bromo-5-methylbenzenamine-->2-BROMO-5-NITROTOLUENE
4-Bromo-3-nitrobenzotrifluoride 4-BROMO-3'-NITROBENZOPHENONE 2-bromo-1,5-dimethyl-3-nitrobenzene 2-bromo-1-(4-bromo-3-nitrophenyl)ethanone 4-(4-BROMO-3-NITRO-PHENYL)-THIAZOL-2-YLAMINE 1-BROMO-2-NITRO-4,5-DI(TRIFLUOROMETHYL)BENZENE 2-NITRO-4-METHYLSULFONYLTOLUENE 3-nitro-4-bromopropiophenone 4-BROMO-3-NITRO-BENZALDEHYDE AKOS 92256 4-BROMO-3-NITROBENZONITRILE METHYL 4-BROMO-3,5-DINITROBENZOATE Methyl 4-bromo-3-nitrobenzoate Nitrotoluol 4-BROMO-3-NITROBIPHENYL, 95 4-Bromo-3-nitrotoluene 4-Bromo-3-nitrobenzoic acid 4-BROMO-3-NITRO-1,8-NAPHTHALIC ANHYDRIDE

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