ChemicalBook Product Catalog Organic Chemistry Organic fluorine compound Fluorobenzonitrile series 2-Amino-6-fluorobenzonitrile

2-Amino-6-fluorobenzonitrile

2-Amino-6-fluorobenzonitrile Basic information
Product Name:2-Amino-6-fluorobenzonitrile
Synonyms:2-FLUORO-6-AMINOBENZONITRILE;2-AMINO-6-FLUOROBENZONITRILE;6-FLUOROANTHRANILONITRILE;6-AMINO-2-FLUOROBENZONITRILE;2-Amino-6-fluorobenzonitrile, 97+% (6-Fluoroanthranilonitrile);Benzonitrile, 2-amino-6-fluoro- (9CI);2-Amino-6-fluorobenzonitrile 98%;2-Amino-6-fluorobenzonitrile98%
CAS:77326-36-4
MF:C7H5FN2
MW:136.13
EINECS:
Product Categories:Aromatic Nitriles;Benzene series;NITRILE;Amines;Aromatics;Miscellaneous Reagents
Mol File:77326-36-4.mol
2-Amino-6-fluorobenzonitrile Structure
2-Amino-6-fluorobenzonitrile Chemical Properties
Melting point 125-128 °C (lit.)
Boiling point 275.8±25.0 °C(Predicted)
density 1.25±0.1 g/cm3(Predicted)
storage temp. 2-8°C
solubility Chloroform
form Solid
pka0.80±0.10(Predicted)
color Pale Yellow
BRN 3588945
CAS DataBase Reference77326-36-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,T,Xn
Risk Statements 36-36/37/38-20/21/22
Safety Statements 26-36-36/37/39-22
RIDADR 3439
WGK Germany 2
Hazard Note Irritant
HazardClass 6.1
PackingGroup III
HS Code 29269090
MSDS Information
ProviderLanguage
2-Amino-6-fluorobenzonitrile English
SigmaAldrich English
ALFA English
2-Amino-6-fluorobenzonitrile Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powder
Uses2-Amino-6-fluorobenzonitrile, a medicinal chemistry intermediate, has been employed for the preparation of tacrine-related compounds. It may be used for the synthesis of antifolate and antibacterial quinazoline derivatives.
It may be used for the synthesis bis(4-oxoquinazolin-2-yl)pyridine and fluoro-containing quinazolin-4(1H)-ones. It may be employed for the synthesis of the following novel huprines:
  • 12-amino-3-chloro-6,7,10,11-tetrahydro-9-isopropyl-7,11-methanocycloocta[b]quinoline hydrochloride
  • 9-allyl-12-amino-3-chloro-6,7,10,11-tetrahydro-7,11-methanocycloocta[b]quinoline hydrochloride
  • 12-amino-1-fluoro-6,7,10,11-tetrahydro-9-isopropyl-7,11-methanocycloocta[b]quinoline hydrochloride
  • 9-allyl-12-amino-1-fluoro-6,7,10,11-tetrahydro-7,11-methanocycloocta[b]quinoline hydrochloride
General Description2-Amino-6-fluorobenzonitrile can be prepared by treatment of 2,6- difluorobenzonitrile with ammonia, which involves displacement of one of the activated fluorine atoms.
2-Amino-6-fluorobenzonitrile Preparation Products And Raw materials
Preparation Products2-AMINO-6-BROMOBENZONITRILE-->4(3H)-Quinazolinone, 5-fluoro-2-phenyl--->2-chloro-5-fluoro-4-methylquinazoline-->2-Bromo-6-fluorobenzonitrile-->1-(2-Amino-6-fluorophenyl)ethanone
2-([3-(DIMETHYLAMINO)PROPYL]AMINO)-6-FLUOROBENZONITRILE Betaine 2-Aminobenzonitrile ALTRENOGEST 2-FLUORO-6-PIPERIDINOBENZONITRILE 2-Amino-6-fluorobenzoic acid 4-Fluorobenzonitrile Glycine 4-Aminobenzonitrile N-(2-CYANO-3-FLUOROPHENYL)PYRROLE 4-Fluorobenzaldehyde N-(2-CYANO-3-FLUOROPHENYL)FORMAMIDE 2-(2-CYANO-3-FLUOROANILINO)ETHYL N-(1,2,2-TRICHLOROVINYL)CARBAMATE 2-Amino-6-fluorobenzonitrile RARECHEM AK HW 0213 AMINO ACIDS Florfenicol 2,4-Dinitrofluorobenzene
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