TRIBUTYL PHOSPHITE

TRIBUTYL PHOSPHITE Basic information
Product Name:TRIBUTYL PHOSPHITE
Synonyms:Tri-n-butylphosphite, min. 94%;Phosphorous acid tributyl;Tributyl phosphite,94%;Tributyl phosphite, 94% 250GR;Tributyl phosphite 90%, technical grade;Tributyl phsophite;TRIBUTYL PHOSPHITE, TECH., 90%;1,1’,1’’-phosphinidynetri-1-butano
CAS:102-85-2
MF:C12H27O3P
MW:250.31
EINECS:203-061-3
Product Categories:organophosphorus compound;Organic Building Blocks;Organic Phosphates/Phosphites;Phosphorus Compounds
Mol File:102-85-2.mol
TRIBUTYL PHOSPHITE Structure
TRIBUTYL PHOSPHITE Chemical Properties
Melting point -80 °C
Boiling point 125 °C
density 0.925 g/mL at 25 °C(lit.)
vapor pressure 3.2Pa at 20℃
refractive index n20/D 1.431(lit.)
Fp 197 °F
solubility Chloroform (Sparingly), Methanol (Slightly)
form liquid
Specific Gravity0.925
color colorless
Water Solubility Not miscible or difficult to mix in water.
Sensitive Air & Moisture Sensitive
BRN 1703866
CAS DataBase Reference102-85-2(CAS DataBase Reference)
EPA Substance Registry SystemTributyl phosphite (102-85-2)
Safety Information
Hazard Codes C
Risk Statements 21-34
Safety Statements 26-36/37/39-45
RIDADR UN 3265 8/PG 3
WGK Germany 3
RTECS TH0875000
TSCA Yes
HS Code 29209085
ToxicityLD50 oral in rat: 3gm/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
TRIBUTYL PHOSPHITE Usage And Synthesis
Chemical PropertiesClear colorless liquid
UsesTributyl phosphite may be employed as model lubricant additive and its surface chemistry on Fe3O4 in ultrahigh vacuum is investigated.
UsesTributyl Phosphite inhibits fluoroacetanilide poisoning in mammals.
UsesTributyl phosphite may be employed as model lubricant additive and its surface chemistry on Fe3O4 in ultrahigh vacuum is investigated.
General DescriptionTributyl phosphite is an alkylphosphite and is reported to inhibit carboxylesterase activity.
Purification MethodsFractionate the phosphite with an efficient column. It is stable in air but is slowly hydrolysed by H2O. [Gerrard J Chem Soc 1464 1940, Fertig et al. J Chem Soc 1488 1957, Fields J Am Chem Soc 80 2358 1958, Gillis et al. J Am Chem Soc 80 2999 1958, Beilstein 1 IV 1527.]
TRIBUTYL PHOSPHITE Preparation Products And Raw materials
Preparation ProductsDI-N-BUTYL SULFATE
TRIDECYL PHOSPHITE PHOSPHOROUS ACID TRI-N-OCTADECYL ESTER PHOSPHOROUS ACID TRIS(2-ETHYLHEXYL) ESTER PHOSPHOROUS ACID TRIOCTYL ESTER TRIAMYL PHOSPHITE O,O,O-TRIBUTYL PHOSPHOROTHIOATE Triisooctyl phosphite TRIHEXYL PHOSPHATE Tributyl phosphate Tris(2-ethylhexyl) phosphate PHOSPHORIC ACID TRI-N-AMYL ESTER PHOSPHOROUS ACID TRIISODECYL ESTER TRILAURYL PHOSPHITE PHOSPHOROUS ACID TRIOLEYL ESTER trioctyl phosphate TRIDECYL ACID PHOSPHATE TRIBUTYL PHOSPHITE TRIHEXYL PHOSPHITE

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