ChemicalBook Product Catalog Organic Chemistry Phosphines DIMETHYL TRIMETHYLSILYL PHOSPHITE

DIMETHYL TRIMETHYLSILYL PHOSPHITE

DIMETHYL TRIMETHYLSILYL PHOSPHITE Basic information
Product Name:DIMETHYL TRIMETHYLSILYL PHOSPHITE
Synonyms:Phosphorous acid, dimethyl trimethylsilyl ester;Dimethoxy[(trimethylsilyl)oxy]phosphine;Trimethylsiloxydimethoxyphosphine;Dimethyl trimethylsilyl phosphite,96%;Dimethyl(trimethylsilyl)phosphite, tech-95;O,O'-DIMETHYL(TRIMETHYLSILYL)PHOSPHITE, tech-95;O,O'-DIMETHYL(TRIMETHYLSILYL)PHOSPHITE;DIMETHYL TRIMETHYLSILYL PHOSPHITE
CAS:36198-87-5
MF:C5H15O3PSi
MW:182.23
EINECS:252-908-3
Product Categories:Organic Building Blocks;Organic Phosphates/Phosphites;Phosphorus Compounds
Mol File:36198-87-5.mol
DIMETHYL TRIMETHYLSILYL PHOSPHITE Structure
DIMETHYL TRIMETHYLSILYL PHOSPHITE Chemical Properties
Boiling point 36-37 °C/11 mmHg (lit.)
density 0.954 g/mL at 25 °C (lit.)
refractive index n20/D 1.410(lit.)
Fp 102 °F
storage temp. 2-8°C
Specific Gravity0.954
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 1849308
Safety Information
Hazard Codes C
Risk Statements 10-34
Safety Statements 26-36/37/39-45
RIDADR UN 2920 8/PG 2
WGK Germany 3
F 10-13
TSCA No
HazardClass 3.2
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
DIMETHYL TRIMETHYLSILYL PHOSPHITE Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesDimethyl trimethylsilyl phosphite may be used in the preparation of:
  • protected phosphoamino acid, Fmoc-Abu(PO3Me2)-OH, used in Fmoc/solid-phase peptide synthesis
  • phosphoenolpyruvate (PEP) via trimethylsilylation, bromination and Perkow reaction
  • sialyl phosphonate
  • sulfonamide phosphonates
DIMETHYL TRIMETHYLSILYL PHOSPHITE Preparation Products And Raw materials
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