10-UNDECEN-1-OL

10-UNDECEN-1-OL Basic information
Product Name:10-UNDECEN-1-OL
Synonyms:10-Undecylenic alcohol;i-undecylenyl alcohol;10-Undecen-1-ol 99%;ALKOHOL C 11 (UNDECEN-1-OL);10-Nndecen-1-ol, 98%;10-Hendecen-1-ol;10-Undecenyl alcohol;ω-Undecenyl alcohol
CAS:112-43-6
MF:C11H22O
MW:170.29
EINECS:203-971-0
Product Categories:omega-Functional Alkanols, Carboxylic Acids, Amines & Halides;omega-Unsaturated Alkanols
Mol File:112-43-6.mol
10-UNDECEN-1-OL Structure
10-UNDECEN-1-OL Chemical Properties
Melting point -3 °C
Boiling point 132-133 °C/15 mmHg (lit.) 245-248 °C (lit.)
density 0.85 g/mL at 25 °C (lit.)
refractive index n20/D 1.45(lit.)
Fp 200 °F
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Sparingly), Methanol (Slightly)
form Liquid
pka15.20±0.10(Predicted)
color Clear colorless
Specific Gravity0.85
Odorat 100.00 %. fresh floral waxy ozone clean citrus
Odor Typecitrus
Water Solubility Miscible with alcohol and ether. Immiscible with water.
BRN 1753225
Stability:Stable. Incompatible with strong acids, strong oxidizing agents.
InChIKeyGIEMHYCMBGELGY-UHFFFAOYSA-N
LogP3.997 (est)
CAS DataBase Reference112-43-6(CAS DataBase Reference)
EPA Substance Registry System10-Undecen-1-ol (112-43-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/38
Safety Statements 37/39-26-24/25
WGK Germany 2
RTECS YQ2985000
Hazard Note Irritant
TSCA Yes
HS Code 29052900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
10-UNDECEN-1-OL Usage And Synthesis
Chemical PropertiesColourless liquid. Soluble in 70% alcohol. Combustible.
Chemical Properties10-Undecen-1-ol is a colorless liquid with a fatty, green, slightly citrus-like odor. It can be synthesized from 10-undecylenic acid and is used to give flower perfumes a fresh note.
OccurrenceReported found in distilled essential oil from leaves of Litsea odorifera Valeton. Also reported found in grilled and roasted beef.
UsesPerfumes.
Uses10-Undecen-1-ol is used as a flavoring agent. It reacts with tosylated beta-cyclodextrin to prepare beta-cyclodextrin undecenylether. It is used in the synthesis of 10-Undecenylacrylat by reacting with acryloyl and triethylamine. It reacts with carbon monoxide in the presence of dicobalt octacarbonyl and pyridine as a base at pressures greater than 150 bar and temperatures in the range of 100 to 2000C to linear and branched polyesters having relatively high molecular weights (Mn> 10,000 g / mol) in good yields.
PreparationPrepared from coconut fatty acids as starting material.
DefinitionChEBI: An alkenyl alcohol that is 1-undecene in which one of the terminal methyl hydrogens is replaced by a hydroxy group.
Synthesis Reference(s)Chemistry Letters, 12, p. 835, 1983
The Journal of Organic Chemistry, 57, p. 3751, 1992 DOI: 10.1021/jo00040a001
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