ChemicalBook Product Catalog Organic Chemistry Carboxylic acids and derivatives Carboxylic acid halides Dimethylthiocarbamoyl chloride

Dimethylthiocarbamoyl chloride

Dimethylthiocarbamoyl chloride Basic information
Product Name:Dimethylthiocarbamoyl chloride
Synonyms:N,N-Dimethylcarbamothioic chloride, tech;DiMethylthiocarbaMoyl Chloride (DMTCC);DiMethylthiocarbaMoyl chloride, 99% 100GR;N,N-Dimethylaminothioformyl;DiMethylthiocarbaMoy;CarbaMothioic chloride,N,N-diMethyl-;DiMethylthiocarbaMoyl chloride 97%;DiMethyl aMinothioxoMethyl chloride
CAS:16420-13-6
MF:C3H6ClNS
MW:123.6
EINECS:240-468-5
Product Categories:Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry;Organic Building Blocks;Sulfur Compounds;Thiocarbonyl Compounds;Thiocarbonyl Compounds
Mol File:16420-13-6.mol
Dimethylthiocarbamoyl chloride Structure
Dimethylthiocarbamoyl chloride Chemical Properties
Melting point 39-43 °C (lit.)
Boiling point 90-95 °C/0.5 mmHg (lit.)
density 1.204 (estimate)
refractive index 1.6100 (estimate)
Fp 209 °F
storage temp. 2-8°C
solubility Soluble in chloroform and tetrahydrofuran.
form Low Melting Crystalline Solid or Crystals
pka0.30±0.50(Predicted)
color Slightly yellow to yellow
Water Solubility reacts
Sensitive Moisture Sensitive
BRN 635823
CAS DataBase Reference16420-13-6(CAS DataBase Reference)
NIST Chemistry ReferenceCarbamothioic chloride, dimethyl-(16420-13-6)
EPA Substance Registry SystemCarbamothioic chloride, dimethyl- (16420-13-6)
Safety Information
Hazard Codes C
Risk Statements 22-34-29-14
Safety Statements 26-36/37/39-45-8-30-22-27
RIDADR UN 3261 8/PG 2
WGK Germany 2
F 10-19-21
Hazard Note Corrosive
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29302000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Dimethylthiocarbamoyl chloride Usage And Synthesis
Chemical Propertiesslightly yellow to yellow low melting crystalline
UsesDimethylthiocarbamoyl chloride is used as an intermediate in the synthesis of pharmaceuticals. It finds application in chemoselective deoxygenation of pyridine-N-oxides. It is also used as a starting reagent in the synthesis of dimethylthiocarbamates.
UsesDimethylthiocarbamoyl chloride was used in chemoselective deoxygenation of pyridine-N-oxides. It was used in the synthesis of (±)-thia-calanolide A. It was used as starting reagent in the synthesis of dimethylthiocarbamates.
Purification MethodsCrystallise it twice from pentane and/or distil it at low pressure. [Beilstein 4 III 147.]
Dimethylcarbamoyl chloride Methylene Chloride Diphenylcarbamyl chloride Calcium chloride Dithiooxamide N-Acetylsulfanilyl chloride Dimethylsulfamoyl chloride Methylaminoformyl chloride Dimethylaminobenzaldehyde Choline chloride Isophthaloyl dichloride Pivaloyl chloride Ammonium chloride Phthaloyl dichloride Dimethylthiocarbamoyl chloride Thionyl chloride N,N-Dimethyl-1,4-phenylenediamine 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile
Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.