ETHYNYLMAGNESIUM CHLORIDE

ETHYNYLMAGNESIUM CHLORIDE Basic information
Product Name:ETHYNYLMAGNESIUM CHLORIDE
Synonyms:ETHYNYLMAGNESIUM CHLORIDE;Ethynylmagnesium chloride, 1.1M solution in THF/toluene;Ethynylmagnesium chloride solution;ETHYNYLMAGNESIUM CHLORIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;Ethynylmagnesium chloride, 0.6M solution in THF/Toluene;EthynylMagnesiuM chloride, 0.6 M solution in THF/toluene, J&KSeal;Ethynylmagnesium chloride solution 0.5 in THF;Ethynylmagnesium chloride, 0.6M solution in THF/Toluene, AcroSeal
CAS:65032-27-1
MF:C2HClMg
MW:84.79
EINECS:
Product Categories:Chemical Synthesis;Grignard Reagents;Alkynyl;Grignard Reagents;Organometallic Reagents;Grignard Reagent;Organometallic Reagents
Mol File:65032-27-1.mol
ETHYNYLMAGNESIUM CHLORIDE Structure
ETHYNYLMAGNESIUM CHLORIDE Chemical Properties
density 0.921 g/mL at 25 °C
Fp −17 °F
storage temp. 2-8°C
form Liquid
color Clear brown to dark brown
Safety Information
Hazard Codes F,C,Xn
Risk Statements 11-14-19-22-34-40-36/37-63-48/20-36/37/38-14/15
Safety Statements 16-26-36/37/39-45-36/37-43B-33-29-6A
RIDADR UN 3399 4.3/PG 2
WGK Germany 1
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ETHYNYLMAGNESIUM CHLORIDE Usage And Synthesis
Chemical Propertiesclear brown to dark brown solution
UsesEthynylmagnesium chloride solution can be used:
  • To synthesize 1-ethynyldeoxyribose derivatives which can further undergo Sonogashira coupling with various aryl, heteroaryl, and metallocenyl derivatives.
  • In one of the key synthetic steps of substituted naphthostyrils.
  • In the preparation of propargylic ester precursor for the synthesis of 1,3-dienylphosphonates.

ETHYNYLMAGNESIUM CHLORIDE Preparation Products And Raw materials
Preparation Products1-PHENYL-2-PROPYN-1-OL-->2-Thiazolemethanol, -alpha--ethynyl--->NSC 89798-->Phosphine, ethynyldiphenyl--->2-Dehydro-3-Methoxy Tibolone
lithium hydrogenacetylide Trimethylsilylacetylene Vinylmagnesium chloride Ethylmagnesium chloride PROPYLMAGNESIUM CHLORIDE ISOPROPYLMAGNESIUM CHLORIDE Allylmagnesium chloride LITHIUM TETRACHLOROCUPRATE LITHIUM ISOPROPOXIDE LITHIUM (TRIMETHYLSILYL)ACETYLIDE Methyltrimethoxysilane Lithium Triethylborohydride Potassium bis(trimethylsilyl)amide 3,4-DIMETHYLPHENYLMAGNESIUM CHLORIDE Methylmagnesium chloride Magnesium monochloride ETHYNYLMAGNESIUM CHLORIDE PHENYLACETYLENEMAGNESIUM CHLORIDE

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