TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE

TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE Basic information
Reaction
Product Name:TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE
Synonyms:TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE;TRI-N-BUTYLPHOSPHINE TETRAFLUOROBORATE,&;Tri-n-butylphosphoniumtetrafluoroborate,99%;tributylphosphine tetrafluoroborate;Tributylphosphonium tetrafluoroborate;Tributylphosphine tetrafluoroborate 97%;[n-Bu3PH]BF4;Tributylphosphine tetrafluoroborate,97%
CAS:113978-91-9
MF:C12H28BF4P
MW:290.13
EINECS:
Product Categories:Achiral Phosphine;Alkyl Phosphine;Catalysis and Inorganic Chemistry;Phosphine Ligands;organophosphine salt;P-BF4;Phosphorus Compounds
Mol File:113978-91-9.mol
TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE Structure
TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE Chemical Properties
Melting point 50-53 °C (lit.)
Fp >221 °F
storage temp. Inert atmosphere,Room Temperature
form Powder
color white
Safety Information
Risk Statements 36/37/38
Safety Statements 22-24/25
WGK Germany 3
HS Code 2931599090
MSDS Information
ProviderLanguage
SigmaAldrich English
TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE Usage And Synthesis
Reaction
  1. Air-stable, non-pyrophoric precursor of the Tri-n-butylphosphine ligand which is used in a variety of catalytic processes.
  2. Catalyst in Baylis-Hillman reactions.
  3. Azide reductions.
  4. Acylation of alcohols by anhydrides.
  5. Ligand for formate reduction of allyl carbonates.
  6. Synthesis of aromatic nitriles via Pd C-H functionalization. 
Reactions of 113978-91-9_1
Reactions of 113978-91-9_2
General DescriptionMay contain approximately 5% of other butyl isomers.
TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE Preparation Products And Raw materials
Raw materialsDichloromethane-->Magnesium sulfate-->Fluoroboric acid-->Tributylphosphine
1-BUTYL-3-METHYLIMIDAZOLIUM ACETATE COBALT TETRAFLUOROBORATE HEXAHYDRATE 1-Butyl-3-methylimidazolium tetrafluoroborate Tri-tert-butylphosphine tetrafluoroborate 1-Butyl-3-methylimidazolium chloride 1-BUTYLPYRIDINIUM TETRAFLUOROBORATE TRIISOPROPYLPHOSPHONIUM TETRAFLUOROBORATE Tri-tert-butylphosphine Phosphonium, [4,5-bis(methoxycarbonyl)-1,3-dithiol-2-yl]tributyl-, tetrafluoroborate(1-) (9-Butyl-9-fluorenyl)dicyclohexylphosphine tetrafluoroborate, cataCXium(R) FBu TRIHEXYL(TETRADECYL)PHOSPHONIUM TETRAFLUOROBORATE TRICYCLOHEXYLPHOSPHONIUM TETRAFLUOROBORATE Tris(dibenzylideneacetone)dipalladium(0)/tri-t-butylphosphonium tetrafluoroborate admixture (molar Pd/P = 1:1.2) TRICYCLOPENTYLPHOSPHINE TETRAFLUOROBORATE TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE Tris(dibenzylideneacetone)dipalladium(0)/tri-t-butylphosphonium tetrafluoroborate admixture (molar Pd/P = 1:2) TETRABUTYLPHOSPHONIUM TETRAFLUOROBORATE cataCXium(R) FPrPh, Dicyclohexyl[9-(3-phenylpropyl)-9-fluorenyl]phosphine tetrafluoroborate

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