1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE

1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE Basic information

Product Name:	1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE
Synonyms:	BIS[(DIISOPROPYLPHOSPHINO)CYCLOPENTADIENYL]IRON;1,1'-BIS(DI-I-PROPYLPHOSPHINO)FERROCENE;1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98%;1,1'-Bis(diisopropylphosphino)ferrocene,98%;1,1'-Bis(di-i-propylphosphino)ferrocene,min.98%;1,1'-Bis[bis(1-methylethyl)phosphino]ferrocene
CAS:	97239-80-0
MF:	C22H36FeP210*
MW:	418.31
EINECS:	677-500-6
Product Categories:	Achiral Phosphine;Aryl Phosphine;Ligand;Ferrocenes;Metallocenes;Phosphine Ligands;Synthetic Organic Chemistry;Catalysis and Inorganic Chemistry;Phosphorus Compounds;Polydentate Phosphine Ligands
Mol File:	97239-80-0.mol

1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE Chemical Properties

Melting point	50-52 °C(lit.)
Fp	>230 °F
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
color	orange-yellow
Water Solubility	Insoluble in water.
CAS DataBase Reference	97239-80-0(CAS DataBase Reference)

Safety Information

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English

1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE Usage And Synthesis

Reaction	Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO. Pd-catalyzed carbonylative ɑ-arylation of ketones with aryl iodides Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation Ligand for ruthenium-catalyzed C—C coupling reactions of fluorinated alcohols with allenes. Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents.
Chemical Properties	orange crystalline powder
Uses	The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE Preparation Products And Raw materials

Raw materials

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