TERT-BUTYL METHYL MALONATE

TERT-BUTYL METHYL MALONATE Basic information

Product Name:	TERT-BUTYL METHYL MALONATE
Synonyms:	T-BUTYL METHYL MALONATE;TERT-BUTYL-(METHYLMALONAT);TERT-BUTYL METHYL MALONATE;Methyl tert-butyl malonate;Propanedioic acid 1,1-dimethylethyl methyl ester;Malonic acid 1-methyl 3-tert-butyl ester;Malonic acid 1-tert-butyl 3-methyl ester;Propanedioic acid 1-(1,1-dimethylethyl)3-methyl ester
CAS:	42726-73-8
MF:	C8H14O4
MW:	174.19
EINECS:	255-919-1
Product Categories:	Aromatic Esters;C8 to C9;Carbonyl Compounds;Esters
Mol File:	42726-73-8.mol

TERT-BUTYL METHYL MALONATE Chemical Properties

Melting point	-10 °C
Boiling point	80 °C11 mm Hg(lit.)
density	1.03 g/mL at 25 °C(lit.)
refractive index	n20/D 1.415(lit.)
Fp	175 °F
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
pka	11.83±0.46(Predicted)
form	Liquid
color	Clear colorless to slightly yellow
BRN	1772136

Safety Information

Safety Statements	23-24/25
WGK Germany	3
HS Code	29171900

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English

TERT-BUTYL METHYL MALONATE Usage And Synthesis

Chemical Properties	clear colorless to slightly yellow liquid
General Description	tert-Butyl methyl malonate is an ester. Stereospecific Pd(O)-catalyzed addition of tert-butyl methyl malonate to allylic carbonates is reported.

TERT-BUTYL METHYL MALONATE Preparation Products And Raw materials

Raw materials	Hydrochloric acid-->Methanol-->Diethyl ether-->Dichloromethane-->Sodium sulfate-->Potassium hydroxide-->Sodium bicarbonate-->tert-Butanol-->4-Dimethylaminopyridine-->tert-Butyl methyl ether-->Dicyclohexylcarbodiimide-->Dimethyl malonate
Preparation Products	Tert-Butyl Methyl 2-(5-Bromopyrimidin-2-Yl)Malonate-->1-tert-Butyl 3-methyl 2-methylmalonate-->2-Pyridineacetic acid, 5-nitro-, methyl ester

TERT-BUTYL ETHYL MALONATE Di-tert-Butyl malonate BENZYL TERT-BUTYL MALONATE 3-ACETYL-3,8,8-TRIMETHYL-2,7-DIOXASPIRO[4.4]NONANE-1,6-DIONE Z-DL-GLA(OTBU)2-OH 3-(2-AMINO-1,3-THIAZOL-4-YL)-3-METHYL-8-(PROPOXYMETHYL)-2,7-DIOXASPIRO[4.4]NONANE-1,6-DIONE Z-D-GLA(OTBU)2-OH 3-[2-(ALLYLAMINO)-1,3-THIAZOL-4-YL]-3,8,8-TRIMETHYL-2,7-DIOXASPIRO[4.4]NONANE-1,6-DIONE 3,8-DIMETHYL-3-{2-[(4-METHYLPHENYL)AMINO]-1,3-THIAZOL-4-YL}-2,7-DIOXASPIRO[4.4]NONANE-1,6-DIONE 4-BROMOMETHYL-5,5-DIMETHYL-2-OXO-2,5-DIHYDRO-FURAN-3-CARBOXYLIC ACID ETHYL ESTER 3-(2-ANILINO-1,3-THIAZOL-4-YL)-3,8-DIMETHYL-2,7-DIOXASPIRO[4.4]NONANE-1,6-DIONE FMOC-TYR(MALONYL-DI-OTBU)-OH TERT-BUTYL METHYL MALONATE 3-(2-AMINO-1,3-THIAZOL-4-YL)-3,8-DIMETHYL-2,7-DIOXASPIRO[4.4]NONANE-1,6-DIONE 4,5,5-TRIMETHYL-2-OXO-2,5-DIHYDRO-FURAN-3-CARBOXYLIC ACID ETHYL ESTER Z-L-GLA(OTBU)2-OH FMOC-GLA(OTBU)2-OH Coumarin 338

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