ChemicalBook Product Catalog Organic Chemistry Amides Naphthenic amines derivatives 4-Nitrodiphenylamine

4-Nitrodiphenylamine

4-Nitrodiphenylamine Basic information
Product Name:4-Nitrodiphenylamine
Synonyms:4-nitro-n-phenylbenzenamine;4-nitro-N-phenyl-benzenamine;Benzenamine, 4-nitro-N-phenyl-;diphenyl,4-nitro-amin;Diphenylamine, 4-nitro-;N-(4-Nitrophenyl)-N-phenylamine;p-Nitrophenylphenylamine;(4-NITROPHENYL)PHENYLAMINE
CAS:836-30-6
MF:C12H10N2O2
MW:214.22
EINECS:212-646-2
Product Categories:Aromatics Compounds;Aromatics;Intermediates of Dyes and Pigments;Amines;C11 to C38;Nitrogen Compounds
Mol File:836-30-6.mol
4-Nitrodiphenylamine Structure
4-Nitrodiphenylamine Chemical Properties
Melting point 132-135 °C (lit.)
Boiling point 211 °C (30 mmHg)
density 1.2042 (rough estimate)
refractive index 1.6660 (estimate)
Fp 190°C
storage temp. Refrigerator
solubility DMSO (Slightly), Methanol (Slightly)
form Solid
pka-2.60±0.20(Predicted)
color Orange to Brown
Water Solubility INSOLUBLE
BRN 2051910
CAS DataBase Reference836-30-6(CAS DataBase Reference)
NIST Chemistry ReferenceN-(4-Nitrophenyl)-N-phenylamine(836-30-6)
EPA Substance Registry System4-Nitrodiphenylamine (836-30-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39-36
RIDADR 3077
WGK Germany 3
RTECS JJ9600000
Hazard Note Irritant
TSCA Yes
HazardClass 9
PackingGroup III
HS Code 29214400
Hazardous Substances Data836-30-6(Hazardous Substances Data)
MSDS Information
ProviderLanguage
4-Nitrodiphenylamine English
SigmaAldrich English
ACROS English
ALFA English
4-Nitrodiphenylamine Usage And Synthesis
Chemical PropertiesOrange Crystalline Solid
Uses4-Nitrodiphenylamine was used to study reduction of nitrated diphenylamine derivatives in sediment water batch enrichments and dense cell suspensions of anaerobic, aromatic-compound-mineralizing pure bacterial cultures.
Synthesis Reference(s)The Journal of Organic Chemistry, 42, p. 1786, 1977 DOI: 10.1021/jo00430a025
General Description4-Nitrodiphenylamine undergoes heterogeneous catalytic transfer hydrogenation to form p-phenylenediamines. 4-Nitrodiphenylamine is used as stabilizer for propellants and explosives.
Purification MethodsCrystallise the amine from EtOH or aqueous EtOH (m 135-136o) and has m 131.5-132o after sublimation in vacuo. [Beilstein 12 H 715, 12 III 1586.]
4-Nitrodiphenylamine Preparation Products And Raw materials
Raw materials2-Nitrodiphenylamine-->2-(Methylamino)pyridine-->Nitrobenzene
Preparation Products4-Aminodiphenylamine-->Disperse Orange 97-->Amoscanate-->Disperse Orange 97-->N-Isopropyl-N'-phenyl-1,4-phenylenediamine
DISPERSE YELLOW 9 2',4'-DINITRO-2,4-DIMETHYLDIPHENYL AMINE Diphenylamine,sulfuric acid solution Phenothiazine 2-Aminodiphenylamine 2',4'-DINITRO-3,4-DIMETHYLDIPHENYLAMINE TIMTEC-BB SBB001082 4-(2,4-DINITROANILINO)PHENOL 2,4,6-TRINITRO-2'-METHYLDIPHENYLAMINE TIMTEC-BB SBB006317 2-Chloro-4-nitroaniline 2,4-Dinitrodiphenylamine 2-Methyl-4-nitroaniline 4-Nitrodiphenylamine ACID YELLOW 65 3,7-dinitrophenothiazine 5-oxide HexanitrodiphenylaMine 4-Aminodiphenylamine
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