ChemicalBook Product Catalog Chemical Reagents Organic reagents Borate 3-CHLORO-4-METHOXYPHENYLBORONIC ACID

3-CHLORO-4-METHOXYPHENYLBORONIC ACID

3-CHLORO-4-METHOXYPHENYLBORONIC ACID Basic information
Product Name:3-CHLORO-4-METHOXYPHENYLBORONIC ACID
Synonyms:AKOS BRN-0653;3-CHLORO-4-METHOXYPHENYLBORONIC ACID;3-CHLORO-4-METHOXYBENZENEBORONIC ACID;B-(3-Chloro-4-methoxyphenyl)boronic acid;4-Borono-2-chloroanisole;(3-chloro-4-Methoxyphenyl)boranediol;3-Chloro-4-methoxyphenylboronic Acid (contains varying amounts of Anhydride);Boronic acid, B-(3-chloro-4-methoxyphenyl)-
CAS:175883-60-0
MF:C7H8BClO3
MW:186.4
EINECS:
Product Categories:Boronic acid;Aryl;Boronic Acids;Boronic Acids and Derivatives;Boronic Acids;blocks;BoronicAcids
Mol File:175883-60-0.mol
3-CHLORO-4-METHOXYPHENYLBORONIC ACID Structure
3-CHLORO-4-METHOXYPHENYLBORONIC ACID Chemical Properties
Melting point 238-242 °C (lit.)
Boiling point 344.8±52.0 °C(Predicted)
density 1.32
storage temp. Inert atmosphere,Room Temperature
solubility soluble in Methanol
pka7.93±0.10(Predicted)
form powder to crystal
color White to Almost white
CAS DataBase Reference175883-60-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39-60-37
WGK Germany 3
HazardClass IRRITANT, KEEP COLD
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
3-CHLORO-4-METHOXYPHENYLBORONIC ACID Usage And Synthesis
Usessuzuki reaction
UsesReactant for:
  • Iron-catalyzed oxidative coupling with benzene derivatives through homolytic aromatic substitution
  • Preparation of microtubule inhibitors as potential antitumors
  • Rhodium/chiral ligand-catalyzed arylation/Dieckmann-type annulation
  • Copper-catalyzed oxidative N-arylation
  • Suzuki and Stille palladium-catalyzed coupling
  • Boron-Heck arylation
3-CHLORO-4-METHOXYPHENYLBORONIC ACID Preparation Products And Raw materials
Raw materials4-BROMO-2-CHLOROANISOLE-->Triisopropyl borate
Preparation Products(4-CHLORO-3-METHOXYPHENYL)BORONICACID
4-BENZYLOXY-3-CHLORO-5-METHYLPHENYLBORONIC ACID 3-Chloro-4-propoxyphenylboronic acid 2-(3,5-Dichloro-4-methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborinane 3-CHLORO-4-(2'-CHLOROBENZYLOXY)PHENYLBO& 2-(4-Benzyloxy-3-chlorophenyl)-4,4,6-trimethyl-1,3,2-dioxaborinane 3,5-DICHLORO-4-METHOXYBENZENEBORONIC ACID 5-CHLORO-2-FLUORO-4-METHOXYPHENYLBORONIC ACID 3-CHLORO-4-(3'-BROMOBENZYLOXY)PHENYLBOR& 2-(4-Benzyloxy-3,5-dichlorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane 4-BUTOXY-3-CHLOROPHENYLBORONIC ACID 4-BENZYLOXY-3-CHLOROPHENYLBORONIC ACID 3-CHLORO-4-(3'-CHLOROBENZYLOXY)PHENYLBO& (5-CHLORO-4-METHOXY-2-METHYLPHENYL)BORONIC ACID 2-(4-Benzyloxy-3-chlorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane AKOS BRN-1179 3-CHLORO-4-ISOPROPOXYPHENYLBORONIC ACID 3-CHLORO-4-(3',5'-DIMETHOXYBENXYLOXY)PH& 3-CHLORO-4-(2'-FLUOROBENZYLOXY)PHENYLBO&
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