Cyclohexanecarbonitrile

Cyclohexanecarbonitrile Basic information
Product Name:Cyclohexanecarbonitrile
Synonyms:Cyclohexanecarboxylic acid nitrile;cyclohexanecarboxylicacidnitrite;hexahydrobenzonitril;TIMTEC-BB SBB008404;CYCLOHEXANECARBONITRILE FOR SYNTHESIS;Cyclohexanecarbonitrile 98%;HEXAHYDROBENZONITRILE;CYANOCYCLOHEXANE
CAS:766-05-2
MF:C7H11N
MW:109.17
EINECS:212-157-4
Product Categories:Pharmaceutical Intermediates;Building Blocks;C6 to C7;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;C6 to C7;Cyanides/Nitriles;Nitrogen Compounds
Mol File:766-05-2.mol
Cyclohexanecarbonitrile Structure
Cyclohexanecarbonitrile Chemical Properties
Melting point 11 °C (lit.)
Boiling point 75-76 °C/16 mmHg (lit.)
density 0.919 g/mL at 25 °C (lit.)
refractive index n20/D 1.4505(lit.)
Fp 149 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form liquid
color Colourless
CAS DataBase Reference766-05-2(CAS DataBase Reference)
NIST Chemistry ReferenceCyclohexanecarbonitrile(766-05-2)
Safety Information
Hazard Codes T
Risk Statements 24/25-36/37/38-23/24/25
Safety Statements 36/37-45-36/37/39-26-23
RIDADR UN 3276 6.1/PG 3
WGK Germany 3
RTECS GU7280000
HazardClass 6.1
PackingGroup 
HS Code 2926907090
MSDS Information
ProviderLanguage
SigmaAldrich English
Cyclohexanecarbonitrile Usage And Synthesis
UsesCyclohexanecarbonitrile was used as model substrate in rhodium-catalyzed direct ortho-arylation reactions of phenylazoles using arylboron reagents. It was used as probe in the synthesis of an asymmetric, C-magnesiated nitrile.
Synthesis Reference(s)Journal of the American Chemical Society, 93, p. 4318, 1971 DOI: 10.1021/ja00746a052
Tetrahedron Letters, 25, p. 3301, 1984 DOI: 10.1016/S0040-4039(01)81369-1
The Journal of Organic Chemistry, 54, p. 4476, 1989 DOI: 10.1021/jo00279a047
Cyclohexanecarbonitrile Preparation Products And Raw materials
Preparation ProductsCyclohexanemethanamine, N-(cyclohexylmethyl)--->1-Phenyl-1-cyclohexanecarbonitrile-->Benzoylcyclohexane-->CYCLOHEXANECARBOXAMIDINE
Cyclohexanecarbonitrile,1-(3-aminophenyl)- Cyclohexanecarbonitrile, 4-ethynyl-4-hydroxy-, cis- (9CI) Cyclohexanecarbonitrile, 4-(acetyloxy)-1-hydroxy-, trans- (9CI) 2,4-DIOXO-6-PHENYL-3-((PYRIMIDIN-2-YLAMINO)METHYLENE)CYCLOHEXANECARBONITRILE Cyclohexanecarbonitrile, 4-ethynyl-4-hydroxy-, trans- (9CI) 1-HYDROXY-1-CYCLOHEXANECARBONITRILE CYCLOHEXANECARBONITRILE, TECH 1-PHENYL-1-CYCLOHEXANECARBONITRILE,Cyclohexanecarbonitrile, 1-phenyl- Cyclohexanecarbonitrile, 1-hydroxy-4-(1-methylethyl)-, cis- (9CI) Cyclohexanecarbonitrile sodium cyanide CYCLOHEXANE-1 4-DICARBONITRILE 98% MIXT& 1,1'-AZOBIS(CYCLOHEXANECARBONITRILE), 98 %,1,1'-azobis(1-cyclohexanecarbonitrile) ,1,1'-AZOBIS(CYCLOHEXANECARBONITRILE) Cyanide Cyclohexanecarbonitrile, 2-ethyl-1-[(trimethylsilyl)oxy]-, (1R,2R)-rel- (9CI) Cyclohexanecarbonitrile, 2-acetyl-1-methyl- (7CI) 4-CYANO-4-(4-FLUOROPHENYL)CYCLOHEXANONE 1-(P-TOLYL)-1-CYCLOHEXANECARBONITRILE

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