PROPARGYLOXYTRIMETHYLSILANE

PROPARGYLOXYTRIMETHYLSILANE Basic information
Product Name:PROPARGYLOXYTRIMETHYLSILANE
Synonyms:Propargyl(trimethylsilyl) ether;triMethyl(prop-2-yn-1-yloxy)silane;Propargyloxytrimethylsilane,97%;3-Trimethylsiloxy-1-propyne,(Propargyloxy)trimethylsilane, O-(Trimethylsilyl)propargyl alcohol, Trimethyl(2-propynyloxy)silane, Trimethyl(propargyloxy)silane;O-TRIMETHYLSILYLPROPARGYL ALCOHOL 98%;3-TriMethylsiloxy-1-propyne 98%;Trimethyl(prop-2-yn-1-yloxy);2-Propynyl trimethylsilyl ether
CAS:5582-62-7
MF:C6H12OSi
MW:128.24
EINECS:226-981-7
Product Categories:Alkynes;Building Blocks;Chemical Synthesis;Organic Building Blocks;Terminal
Mol File:5582-62-7.mol
PROPARGYLOXYTRIMETHYLSILANE Structure
PROPARGYLOXYTRIMETHYLSILANE Chemical Properties
Melting point <0°C
Boiling point 52 °C85 mm Hg(lit.)
density 0.835 g/mL at 25 °C(lit.)
refractive index n20/D 1.408(lit.)
Fp 48 °F
storage temp. Flammables area
form Liquid
Specific Gravity0.833
color Clear yellow-brown
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Sensitive Moisture Sensitive
BRN 2036793
CAS DataBase Reference5582-62-7(CAS DataBase Reference)
EPA Substance Registry SystemSilane, trimethyl(2-propynyloxy)- (5582-62-7)
Safety Information
Hazard Codes F
Risk Statements 11
Safety Statements 16-23-24/25
RIDADR UN 1993 3/PG 2
WGK Germany 3
21
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
PROPARGYLOXYTRIMETHYLSILANE Usage And Synthesis
Chemical PropertiesCLEAR YELLOW-BROWN LIQUID
Uses3-Trimethylsiloxy-1-propyne (Trimethyl(2-propynyloxy)silane) may be used in the synthesis of polytrialkylsiloxy-substituted macromolecules. It may be utilized in the preparation of functionalized 4-enynes and 1,4-dienes.
General Description3-Trimethylsiloxy-1-propyne is an organosilicon compound. It is reported as silylated acetylenic monomer and its polymerizability has been studied in the presence of combined catalyst iron(III) propanoate-triethylaluminium. N2 laser light-induced aerosol particle formation from 3-trimethylsiloxy-1-propyne (trimethyl(2-propynyloxy)silane) and acrolein has been reported. The infrared laser-photosensitized (SF6) decomposition of trimethyl(2-propynyloxy)silane is reported to afford a multitude of unsaturated hydrocarbons and a solid polydimethylsiloxane phase.
TERT-BUTYLDIMETHYL(2-PROPYNYLOXY)SILANE ETHYL 4-(TRIMETHYLSILYLOXY)-2-BUTYNOATE 4-(TERT-BUTYL-DIMETHYL-SILANYLOXY)-BUT-2-YNOIC ACID TRIMETHYLSILANE 2-TRIMETHYLSILYLOXY-3-BUTYNE Propyne 2-((3-TERT-BUTYLDIMETHYLSILYLOXY)-1-BUTYN-1-YL)-4,4,5,5-TETRAMETHYL-(1,3,2)DIOXABOROLANE 3-METHYL-3-TRIMETHYLSILYLOXY-1-BUTYNE TRIMETHYLSILYL ACETYLENECARBOXYLATE 4-(TERT-BUTYL-DIMETHYL-SILANYLOXY)-BUT-2-YNOIC ACID METHYL ESTER 2-TERT-BUTYLDIMETHYLSILOXYBUT-3-YNE PROPARGYLOXYTRIMETHYLSILANE BIS(TRIMETHYLSILYL)ACETYLENEDICARBOXYLATE TRIMETHYLSILYL(TRIMETHYLSILYL)PROPYNOATE

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