ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Rare-Earth Metal TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III)

TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III)

TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) Basic information
Product Name:TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III)
Synonyms:N,N-BIS(TRIMETHYLSILYLAMINE)CERIUM(III);TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III);HEXAMETHYLDISILAZANE CERIUM(III) SALT;CERIUM III TRIS(BIS(TRIMETHYLSILYLAMIDE));Ceriumtrisbistrimethylsilylamide;TrisN,N-bis(trimethylsilyl)amideücerium(III), 98%;CERIUM III TRIS[BIS(METHYLSILYLAMIDE)];Cerium(3+) bis(trimethylsilyl)amide
CAS:41836-21-9
MF:C6H19CeNSi2
MW:301.51
EINECS:
Product Categories:CeriumVapor Deposition Precursors;Catalysis and Inorganic Chemistry;Cerium;Chemical Synthesis;Precursors by Metal
Mol File:41836-21-9.mol
TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) Structure
TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) Chemical Properties
Melting point 132-140 °C(lit.)
Boiling point 95-9°C/10-4mmHg
Fp 36 °F
storage temp. Flammables + water-Freezer (-20°C)e area
form Powder
Water Solubility Soluble in water, protic solvents.
Sensitive Moisture Sensitive
Safety Information
Hazard Codes F,C
Risk Statements 11-14/15-34
Safety Statements 16-26-36/37/39-43-45-7/8
RIDADR UN 3396 4.3/PG 2
WGK Germany 3
TSCA No
HazardClass 4.1
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) Usage And Synthesis
Chemical PropertiesBright yellow crystalline powder
UsesTris[N,N-bis(trimethylsilyl)amide]cerium(III) is used as a reactant for synthesis of amidocerium(IV) oxides, Sterically encumbered N-heterocyclic carbene ligands, Lanthanide imidodiphosphinate complexes with electroluminescent properties, Lanthanide complexes of an oxazoline-phenoxide hybrid chelate. Some of the other applications include it is used as a reactant for One-electron oxidation to produce tetravalent cerium compounds, Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes.
TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) Preparation Products And Raw materials
Raw materialsCERIUM(III) TRIFLUOROMETHANESULFONATE-->Sodium bis(trimethylsilyl)amide
POLY(DIMETHYLSILOXANE), HYDROXY TERMINATED RHENIUM TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) Hexamethyldisilazane CERIUM Cesium
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