p-Fluorotoluene

p-Fluorotoluene Basic information

Product Name:	p-Fluorotoluene
Synonyms:	Benzene,1-fluoro-4-methyl-;p-Fluoromethylbenzene;p-fluoro-toluen;p-Tolylfluoride;Toluene, p-fluoro-;toluene,p-fluoro-;4-FLUOROTOLUENE;PARA FLUORO TOLUENE
CAS:	352-32-9
MF:	C7H7F
MW:	110.13
EINECS:	206-520-6
Product Categories:	C7-C8;Aryl Fluorinated Building Blocks;Building Blocks;Chemical Synthesis;Fluorinated Building Blocks;Halogenated Hydrocarbons;Aromatic Hydrocarbons (substituted) & Derivatives;Aryl;C7;Halogenated Hydrocarbons;Organic Building Blocks;Organic Fluorinated Building Blocks;Other Fluorinated Organic Building Blocks;alkyl Fluorine
Mol File:	352-32-9.mol

p-Fluorotoluene Chemical Properties

Melting point	-56 °C (lit.)
Boiling point	116 °C (lit.)
density	1 g/mL at 25 °C (lit.)
refractive index	n20/D 1.468(lit.)
Fp	63 °F
storage temp.	Flammables area
solubility	200mg/l
form	Liquid
Specific Gravity	1.000
color	Clear colorless to slightly yellow
Water Solubility	immiscible
Merck	14,4180
BRN	1362373
Stability:	Volatile
CAS DataBase Reference	352-32-9(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-fluoro-4-methyl-(352-32-9)
EPA Substance Registry System	p-Fluorotoluene (352-32-9)

Safety Information

Hazard Codes	F,Xn,Xi
Risk Statements	11-20/21/22-36/37/38
Safety Statements	7-16-36/37-37/39-26
RIDADR	UN 2388 3/PG 2
WGK Germany	3
RTECS	XT2580000
Hazard Note	Flammable
TSCA	T
HazardClass	3
PackingGroup	II
HS Code	29036990

MSDS Information

Provider	Language
p-Fluorotoluene	English
ACROS	English
SigmaAldrich	English
ALFA	English

p-Fluorotoluene Usage And Synthesis

Chemical Properties	clear colorless to slightly yellow liquid
General Description	A colorless liquid with an aromatic odor. May float or sink in water.
Air & Water Reactions	Highly flammable.
Reactivity Profile	p-Fluorotoluene may be incompatible with strong oxidizing and reducing agents. May be incompatible with amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Products of combustion contain toxic fluoride fumes.
Health Hazard	INHALATION: Irritation of respiratory system. EYES AND SKIN: Severe irritation. INGESTION: Severe internal damage if swallowed.
Fire Hazard	Special Hazards of Combustion Products: Toxic fumes of fluoride
Safety Profile	Moderately toxic by parenteral route. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxibzing materials. When heated to decomposition it emits toxic fumes of F-. See also FLUORIDES.
Purification Methods	Purify it as for o-fluorotoluene. [Beilstein 5 H 290, 5 III 677, 5 IV 799.]

p-Fluorotoluene Preparation Products And Raw materials

Raw materials	p-Toluidine-->CH3-->Methyl, (4-methylphenyl)--->2,4-Difluorotoluene-->2,5-Difluorotoluene-->2-Fluoro-p-Xylene-->3,4-Difluorotoluene-->3-Fluorotoluene
Preparation Products	4-Chlorobenzotrifluoride-->4-Fluorobenzaldehyde-->(4-FLUORO-PHENYL)-METHANESULFONYL CHLORIDE-->1,3-Bis(trifluoromethyl)-benzene-->1,2-BIS-(4-FLUOROPHENYL)ETHANONE-->4-Fluoro-3-nitrobenzoic acid-->DI-P-TOLYLMETHANE-->4-nitro-6-fluoroindazole-->4-METHOXY-3-NITROBENZOTRIFLUORIDE-->2-Fluoro-5-methylbenzaldehyde-->2-Methoxy-5-(trifluoromethyl)aniline

4-Fluorostyrene 4,4'-Difluorobiphenyl Decafluorobiphenyl 4'-Fluoropropiophenone OCTAFLUOROTOLUENE Bis(4-fluorophenyl)-methanone 2-Chloro-4'-fluorobenzophenone 2-Chloro-4-fluorotoluene,98%,2-Chloro-4-fluorotoluene 98% 4,4'-Difluorobenzhydrol METHYL 4-FLUOROBENZOYLACETATE DECAFLUOROBENZOPHENONE 4-Fluoroacetophenone 2',3',4',5',6'-PENTAFLUOROACETOPHENONE 2,4-Difluorotoluene p-Fluorotoluene PENTAFLUOROBENZYL BROMIDE 2,3,4,5,6-PENTAFLUOROBENZOPHENONE DECAFLUOROBENZHYDROL

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