2,2,2-Tribromoethanol

2,2,2-Tribromoethanol Basic information
Product Name:2,2,2-Tribromoethanol
Synonyms:NARKOLAN;2,2,2-TRIBROMOETHANOL;ETHOBROM;BETA-TRIBROMOETHYL ALCOHOL;B-TRIBROMOETHYL ALCOHOL;BROMETHOL;2,2,2-tribromo-ethano;2,2,2-Tribromoethyl alcohol
CAS:75-80-9
MF:C2H3Br3O
MW:282.76
EINECS:200-903-1
Product Categories:Halogen compounds;bc0001
Mol File:75-80-9.mol
2,2,2-Tribromoethanol Structure
2,2,2-Tribromoethanol Chemical Properties
Melting point 73-79 °C(lit.)
Boiling point 92-93 °C10 mm Hg(lit.)
density 2.5731 (rough estimate)
refractive index 1.6210 (estimate)
Fp 92-93°C/10mm
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form powder to crystal
pka13.41±0.10(Predicted)
color Crystals, needles, or prisms
Odorethereal odor
Water Solubility Soluble in alcohol, ether, benzene and warmpetroleum ether. Partially soluble in water.
Sensitive Light Sensitive
BRN 1733249
CAS DataBase Reference75-80-9(CAS DataBase Reference)
NIST Chemistry ReferenceEthanol, 2,2,2-tribromo-(75-80-9)
EPA Substance Registry SystemEthanol, 2,2,2-tribromo- (75-80-9)
Safety Information
Hazard Codes Xn
Risk Statements 22-36/37/38
Safety Statements 26-36
WGK Germany 3
RTECS KM3675000
8-23
TSCA Yes
HS Code 29159080
ToxicityLD50 orally in rats: 1.09 g/kg (Burtner, Lehmann)
MSDS Information
ProviderLanguage
2,2,2-Tribromoethanol English
SigmaAldrich English
ACROS English
ALFA English
2,2,2-Tribromoethanol Usage And Synthesis
Chemical PropertiesWhite crystals or powder; slight aromatic odor and taste. Unstable in air and light. Slightly soluble in water; soluble in alcohol, ether, benzene, and amylene hydrate; aqueous and alcoholic solutions decompose on exposure to light. Combustible.
Uses2,2,2-Tribromoethanol can be used as a functional initiator for the introduction of α-hydroxyl groups to poly(methyl methacrylate) and poly(n-butyl acrylate).
UsesMedicine (basal anesthetic).
Uses2,2,2-Tribromoethanol is utilized in organic synthesis of beta-amino alcohols. The pharmaceutical preparation of tribromoethanol serves as an anesthetic in medicine.
DefinitionChEBI: Tribromoethanol is an organobromine compound and an alcohol.
General Description2,2,2-Tribromoethanol is generally used as an anesthetic drug for rodents.
Safety ProfilePoison by intravenous and intraperitoneal routes. Moderately toxic by ingestion and other routes. Dangerous when heated; see also BROMIDES.
2,2,2-Tribromoethanol Preparation Products And Raw materials
Preparation Products2,2,2-tribromoethyl chloroformate-->2,2,2-TRIBROMOETHYL DICHLOROPHOSPHATE
VANADIUM(III) ACETYLACETONATE Tribromoacetaldehyde Phosphorus tribromide benzyl tribromoacetate 2,2,2-TRIBROMOETHYL PHOSPHOROMORPHOLINOCHLORIDATE RARECHEM AL BI 0117 RARECHEM AL BP 0117 Benzenesulfonic acid, p-nitro-, 2,2,2-tribromoethyl ester 2,2,2-TRIFLUOROETHANOL-D3 Phosphorus oxybromide 2,2,2-TRIBROMOETHYL DICHLOROPHOSPHATE 4-TERT-BUTYL-2-CHLOROPHENYL-2,2,2-TRIBROMOETHYL PHOSPHOROCHLORIDATE 2,2,2-Tribromoethanol 2,2-Difluoroethanol METHYL TRIBROMOACETATE, 99 METHYL-D3 TRIBROMOACETATE, 98 ATOM % D TRIBROMOACETIC ACID-1-13C 1,1,1-TRIBROMO-4-PHENYL-BUT-3-YN-2-OL

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