ChemicalBook Product Catalog Chemical Reagents Organic reagents Boric acid 2-Benzyloxyphenylboronic acid

2-Benzyloxyphenylboronic acid

2-Benzyloxyphenylboronic acid Basic information
Product Name:2-Benzyloxyphenylboronic acid
Synonyms:AKOS BRN-0079;2-Benzyloxyphenylboronic Acid (contains varying amounts of Anhydride);2-BENZYLOXYBENZENEBORONIC ACID;2-BENZYLOXYPHENYLBORONIC ACID;RARECHEM AH PB 0042;O-BENZYLOXYPHENYLBORONIC ACID;2-Phenylmethoxy Phenylboronic Acid;2-BENZYLOXYPHENYLBORORNIC ACID
CAS:190661-29-1
MF:C13H13BO3
MW:228.05
EINECS:
Product Categories:Boronic Acids and Derivatives;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;Organometallic Reagents;Boronate Ester;Potassium Trifluoroborate;blocks;Boronic acids;Boronic acid;Organoborons;Aryl;Boronic Acids;Boronic Acids and Derivatives;Aryl Boronic Acids;BoronicAcids
Mol File:190661-29-1.mol
2-Benzyloxyphenylboronic acid Structure
2-Benzyloxyphenylboronic acid Chemical Properties
Melting point 105-110 °C(lit.)
Boiling point 428.7±47.0 °C(Predicted)
density 1.20±0.1 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Dichloromethane, Ethyl Acetate, Methanol
pka8.57±0.53(Predicted)
form Solid
color White
BRN 7813704
CAS DataBase Reference190661-29-1(CAS DataBase Reference)
Safety Information
Hazard Codes C,Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39-36
WGK Germany 3
Hazard Note Corrosive
HazardClass IRRITANT, CORROSIVE
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
2-Benzyloxyphenylboronic acid Usage And Synthesis
Chemical PropertiesWhite Solid
Uses2-Benzyloxyphenylboronic acid is a reagent used in the preparation of different kinase inhibitors.
UsesPalladium complex-catalyzed selective hydroxylation ? Palladium(II)-catalyzed oxidative Heck reactions ? Metal-free electrophilic fluorination ? Suzuki-Miyaura cross-coupling reactions
UsesReactant for:• ;Palladium complex-catalyzed selective hydroxylation1• ;Palladium(II)-catalyzed oxidative Heck reactions2• ;Metal-free electrophilic fluorination3• ;Suzuki-Miyaura cross-coupling reactions4
Usessuzuki reaction
2-Benzyloxyphenylboronic acid Preparation Products And Raw materials
Raw materialsTetrahydrofuran-->N,N-Dimethylformamide-->Potassium carbonate-->n-Butyllithium-->Benzyl chloride-->Trimethyl borate-->2-Bromophenol
4-Tolylboronic acid 2-BENZYLOXY-3-BROMO-5-METHYLPHENYLBORON& 3-BROMO-5-METHYL-2-(3'-METHOXYBENZYLOXY& 4-Methoxybenzyl alcohol 2-(3'-CHLOROBENZYLOXY)PHENYLBORONIC ACID 2-BENZYLOXY-5-FORMYL-3-METHOXYBENZENEBORONIC ACID 3-BROMO-2-(3'-BROMOBENZYLOXY)-5-METHYLP& 2-BENZYLOXYPHENYLBORONIC ACID, PINACOL ESTER,2-(2-Benzyloxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 2-Benzyloxyphenylboronic acid pinacol ester Anisole 4-Methoxyphenylacetic acid 3-BROMO-2-(3'-BROMOBENZYLOXY)PHENYLBORO& 2-Benzyloxyphenylboronic acid 2-(2'-Chlorobenzyloxy)phenylboronic acid 2-BENZYLOXY-4-FLUOROPHENYLBORONIC ACID 2-Benzyloxy-5-fluorophenylboronic acid 2-Phenoxyethanol Citric acid 3-BROMO-2-(4'-FLUOROBENZYLOXY)-5-METHYL&
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