2-Nitroso-1-naphthol

2-Nitroso-1-naphthol Basic information
Product Name:2-Nitroso-1-naphthol
Synonyms:C.I.Oxidation Base 15;2-Nitroso-1-naphthol,95%;1,2-NaphthoquinoneiMine-2-oxiMe;1-Naphthalenol,2-nitroso-;1-Naphthol, 2-nitroso-;2-nitroso-1-naphthaleno;Nitroso-1-napht;2-nitroso-1-Naphthalenol
CAS:132-53-6
MF:C10H7NO2
MW:173.17
EINECS:205-064-5
Product Categories:Organic Building Blocks;Intermediates of Dyes and Pigments;Piperazine derivates;Nitroso Compounds;Nitrogen Compounds
Mol File:132-53-6.mol
2-Nitroso-1-naphthol Structure
2-Nitroso-1-naphthol Chemical Properties
Melting point 150-155 °C (dec.)(lit.)
Boiling point 303.81°C (rough estimate)
density 1.2427 (rough estimate)
refractive index 1.5200 (estimate)
pka7.47±0.10(Predicted)
form Solid
color Yellow needles from H2O or C6H6
OdorOdorless
Water Solubility SLIGHTLY SOLUBLE
BRN 1867919
CAS DataBase Reference132-53-6(CAS DataBase Reference)
NIST Chemistry Reference1-Naphthalenol, 2-nitroso-(132-53-6)
EPA Substance Registry System1-Naphthalenol, 2-nitroso- (132-53-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
RTECS QL4550000
8
HS Code 2929900090
Hazardous Substances Data132-53-6(Hazardous Substances Data)
ToxicityLD orl-rat: >500 mg/kg NCNSA6 5,35,53
MSDS Information
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2-Nitroso-1-naphthol Usage And Synthesis
Chemical Propertiesyellow-greenish to yellow-brownish powder
General Description2-nitroso-1-naphthol helps in the extraction of cobalt ion as it is used as a selective complexing agent. It is used in the separation and preconcentration of Th(IV), Ti(IV), Fe(III), Pb(II) and Cr(III) by solid phase extraction.
Safety ProfileModerately toxic by ingestion. Many nitroso compounds are carcinogens. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of NOx. See also NITROSO COMPOUNDS.
Purification MethodsPurify the naphthol by recrystallisation from pet ether (b 60-80o) or by dissolving it in hot EtOH, followed by successive addition of small volumes of water (m 158o dec). It also crystallises from *C6H6 or H2O. Crystallisation from *C6H6/pet ether gives m (106-109 o, also 109.5o). It has max at 274.5 and 382nm (CHCl3). It complexes with metals. [Beilstein 7 H 712, 7 I 385, 7 II 647, 7 III 3688, 7 IV 2419.]
4-AMINO-2-NITRO-1-NAPHTHOL 1,1'-Bi-2-naphthol H-ARG(ME)-OH FLAVIANATE 4-NITRO-1,2-DIHYDRO-5-ACENAPHTHYLENOL FLAVIANIC ACID H-ARG(NH2)-OH FLAVIANATE 1,4-DIMETHOXY-2-NITRONAPHTHALENE 7-Hydroxyaristolochic acid A BARIUM FLAVIANATE 2- 1-NITROSO-2-NAPHTHOL 2,4-DINITRO-1-NAPHTHYL-P-TOSYLATE 2,4-DINITROSO-1,3-NAPHTHALENEDIOL NITROSOGUANIDINE 2-NITROSO-1-NAPHTHOL-4-SULFONIC ACID HYDRATE 1-NITROSO-2-NAPHTHOL-3,6-DISULFONIC ACID DISODIUM SALT,DISODIUM 1-NITROSO-2-NAPHTHOL-3,6-DISULFONATE 2-NITROSO-1-NAPHTHOL-4-SULFONIC ACID FOR SPECTROPHOTOM. DET. 99+%,2-NITROSO-1-NAPHTHOL-4-SULPHONIC ACID TETRAHYDRATE,2-NITROSO-1-NAPHTHOL-4-SULFONIC ACID 3-nitro-5H-phenanthro(4,5-bcd)pyran-5-one 4-BROMO-2-NITRO-1-NAPHTHALENOL

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