ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organotin TRIBUTYL(1-ETHOXYVINYL)TIN

TRIBUTYL(1-ETHOXYVINYL)TIN

TRIBUTYL(1-ETHOXYVINYL)TIN Basic information
Reaction
Product Name:TRIBUTYL(1-ETHOXYVINYL)TIN
Synonyms:(1-Ethoxyvinyl)tributyltin(IV);[1-(Tributylstannyl)vinyl]ethyl ether;1-Ethoxy-1-(tributylstannyl)ethene;1-Ethoxyethenyltributylstannane;Tributyl(1-ethoxyvinyl)stannane;Tributyl(1-ethoxyvinyl)tin(IV);Tributyl(1-ethoxyvinyl)tin,95%;ETHOXYVINYL TRIBUTYL TIN
CAS:97674-02-7
MF:C16H34OSn
MW:361.15
EINECS:
Product Categories:Organotin;Organotins;Organometallic Reagents;Stannanes
Mol File:97674-02-7.mol
TRIBUTYL(1-ETHOXYVINYL)TIN Structure
TRIBUTYL(1-ETHOXYVINYL)TIN Chemical Properties
Melting point <0°C
Boiling point 85-86 °C0.1 mm Hg(lit.)
density 1.069 g/mL at 25 °C(lit.)
refractive index n20/D 1.476(lit.)
Fp >230 °F
storage temp. 2-8°C
solubility Choroform (Slightly), Ethyl Acetate (Slightly)
form liquid
color colorless
Specific Gravity1.069
Sensitive Moisture Sensitive
InChIKeyHGXJOXHYPGNVNK-UHFFFAOYSA-N
Safety Information
Hazard Codes T,N
Risk Statements 21-25-36/38-48/23/25-50/53
Safety Statements 35-36/37/39-45-60-61
RIDADR UN 2788 6.1/PG 3
WGK Germany 3
TSCA No
HazardClass 6.1(b)
PackingGroup III
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
TRIBUTYL(1-ETHOXYVINYL)TIN Usage And Synthesis
ReactionVersatile tin reagent used for the introduction of a 1-ethoxyvinyl group via a Stille cross-coupling reaction, (palladium-catalyzed coupling of an organohalide (or pseudohalide) with an organotin compound). Reactions of 97674-02-7
Chemical PropertiesClear colorless liquid
UsesElectrophilic methyl ketone equivalent used in a recent synthesis of a 13-oxophorbine (chlorophyll) from the corresponding 13-bromochlorin.
General DescriptionThis vinylstannane undergoes Stille coupling with a vinyl triflate, giving, after hydrolysis, an α,β?unsaturated ketone, thus acting as an acetyl anion equivalent.
TRIBUTYL(1-ETHOXYVINYL)TIN Preparation Products And Raw materials
Preparation Products1-(3-AMINO-PYRIDIN-2-YL)-ETHANONE-->1-QUINOLIN-3-YLETHANONE-->1-(1-BROMONAPHTHALEN-4-YL)ETHANONE-->2'-hydroxy-5'-(trifluoroMethyl)acetophenone-->3-IODOBENZYL ALCOHOL-->Benzonitrile, 4-acetyl-3-fluoro--->4-Methyl-3-nitroacetophenone-->5-ACETYL-2-METHOXYPYRIDINE, 97%-->4-Pyrimidinamine, 6-(1-ethoxyethenyl)--->1-(3-Fluoro-5-nitrophenyl)ethanone-->Ethanone, 1-(2,1,3-benzoxadiazol-5-yl)- (9CI)-->3-chloro-6-(1-ethoxyethenyl)Pyridazine-->Ethanone, 1-(1H-pyrrolo[3,2-b]pyridin-5-yl)--->3-(1-Ethoxyvinyl)-4-Methylpyridine
Homopiperazine ZINC TRIFLUOROMETHANESULFONATE Z-(1)-ETHOXY-(2)-(TRIBUTYLSTANNYL)ETHYLEN TETRAMETHYLTIN Tributyl(vinyl)tin triethyltin (1-ETHOXYVINYL)TRIMETHYLSTANNANE TRIPROPYLTIN 2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN Tributyltin Hydride TRIBUTYL(1-ETHOXYVINYL)TIN TRI-N-BUTYLMETHYLTIN Ethyltrimethyltin(IV)
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