4-BROMOBENZHYDROL

4-BROMOBENZHYDROL Basic information
Product Name:4-BROMOBENZHYDROL
Synonyms:LABOTEST-BB LT00159467;BENZOPHENONE-4-CARBOXYLIC ACID;4-BENZOYLBENZOIC ACID;4-CARBOXY BENZOPHENONE;(+/-)-4-BROMOBENZHYDROL;4-BROMOBENZHYDROL;P-BENZOYLBENZOIC ACID;P-BROMOBENZHYDROL
CAS:611-95-0
MF:C14H10O3
MW:226.23
EINECS:210-286-0
Product Categories:Functional Materials;Photopolymerization Initiators;Aromatic Benzophenones & Derivatives (substituted)
Mol File:611-95-0.mol
4-BROMOBENZHYDROL Structure
4-BROMOBENZHYDROL Chemical Properties
Melting point 198-200 °C (lit.)
Boiling point 327.84°C (rough estimate)
density 1.2022 (rough estimate)
refractive index 1.5767 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
pka3.79±0.10(Predicted)
form Crystalline Powder
color White to light beige
Water Solubility It is soluble in water (partly).
BRN 1960224
Stability:Stable. Incompatible with strong bases, strong oxidizing agents.
CAS DataBase Reference611-95-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 22-24/25-36-26-37/39
WGK Germany 3
RTECS DG3650000
Hazard Note Irritant
HS Code 29145090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
4-BROMOBENZHYDROL Usage And Synthesis
Chemical Propertieswhite crystalline solid
Uses4-Benzoylbenzoic acid,is a important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field etc.
Uses4-Benzoylbenzoic acid, along with methacrylic acid can be used as ligands for synthesizing a novel Tb(III) ternary complex with luminescent property.
General Description4-Benzoylbenzoic acid is a benzophenone derivative. It can undergo hydrogenolysis to 4-benzylbenzoic acid. Cotton fabrics incorporated with 4-benzoylbenzoic acid have shown pesticide degradation ability, when exposed to UV irradiation.
HazardA poison.
Safety ProfileA poison by intravenous route.When heated to decomposition it emits acrid smoke andirritating vapors.
Purification MethodsDissolve the acid in hot H2O by adding enough aqueous KOH solution till distinctly alkaline, filter and then acidify with drops of conc HCl. Filter off, wash the solid with cold H2O, dry it at 100o, and recrystallise it from EtOH. [Wertheim J Am Chem Soc 55 2540 1933, Beilstein 10 H 753, 10 IV 3305.]
4-BROMOBENZHYDROL Preparation Products And Raw materials
Preparation Products4-benzylbenzoyl chloride-->4-[(S)-[(2S,5R)-2,5-DIMETHYL-4-(2-PROPENYL)-1-PIPERAZINYL]PHENYLMETHYL]-N,N-DIETHYLBENZAMIDE
4,4'-Carbonyldiphthalic acid RHEIN-8-GLUCOSIDE Carminic Acid ETH 2041 BENZOPHENONE-4,4'-DICARBOXYLIC ACID Sennoside B 1-amino-9,10-dihydro-9,10-dioxo-2-anthracenecarboxylicaci LABOTEST-BB LT00053584 4-BENZOYLBENZOIC ACID SUCCINIMIDYL ESTER 7-OXO-7H-BENZO[E]PERIMIDINE-4-CARBOXYLIC ACID BENZOPHENONE-ALPHA-13C-3,3',4,4'-TETRACARBOXYLIC DIANHYDRIDE 3,3',4,4'-Benzophenonetetracarboxylic dianhydride Sennoside A 1-amino-4-bromo-9,10-dioxo-9,10-dihydroan thracene-2-carboxylic acid 4-BROMOBENZHYDROL SODIUMCARMINE Carmine SENNOSIDE

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