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| Product Name: | XPhos Pd G3 | | Synonyms: | XPhos Pd G3;Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);(2-Dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate;Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [XPhos Palladacycle];Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%;XPhos-G3-Palladacycle;XPhos Pd G3 95%;(SP-4-3)-[2'-(Amino)[1,1'-biphenyl]-2-yl][dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium | | CAS: | 1445085-55-1 | | MF: | C46H62NO3PPdS | | MW: | 846.46 | | EINECS: | | | Product Categories: | Buchwald Ligands&Precatalysts;Buchwald Precatalysts Series;Pd | | Mol File: | 1445085-55-1.mol |  |
| | XPhos Pd G3 Chemical Properties |
| Melting point | 146-151°C (decomposition) | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | Powder | | color | white to off-white |
| Risk Statements | 52/53 | | Safety Statements | 61 | | WGK Germany | 3 | | HS Code | 2843909000 |
| | XPhos Pd G3 Usage And Synthesis |
| Reaction | Palladium precatalyst for facile C-N cross-coupling reactions.
| | Uses | XPhos Pd G3 may be used in the following reactions:
- Cyanation reaction of heterocyclic halides.
- Coupling of heteroaryl chlorides with polyfluoroaryl zinc reagents.
- Coupling of 2,6-difluorophenylboronic acid with (hetero)aryl chlorides.
| | Uses | Convenient dosable form of XPhos-Pd-G3.
0.025 mmoles per capsule (1EA = 0.025 mmoles) | | General Description | XPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XPhos Pd G3 is an excellent reagent for Suzuki cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio. |
| | XPhos Pd G3 Preparation Products And Raw materials |
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