TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE

TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Basic information
Product Name:TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
Synonyms:tris(3,5-dimethylphenyl)-phosphin;TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE;TRIS(3,5-XYLYL)PHOSPHINE;TRI(3,5-XYLYL)PHOSPHINE;Tris(3,5-dimethylphenyl)phosphine,98%;TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE, 97+%;Tri(3,5-dimethylphenyl)phosphine;Tris(3,5-dimethylphenyl)phosphineTris(3,5-xylyl)phosphine
CAS:69227-47-0
MF:C24H27P
MW:346.44
EINECS:624-162-2
Product Categories:Aryl Phosphine;Achiral Phosphine;Ligand;Catalysis and Inorganic Chemistry;Phosphine Ligands;organophosphorus ligand;Phosphorus Compounds
Mol File:69227-47-0.mol
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Structure
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Chemical Properties
Melting point 160-165 °C
Boiling point 474.1±45.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
form crystal
color white
EPA Substance Registry SystemPhosphine, tris(3,5-dimethylphenyl)- (69227-47-0)
Safety Information
Hazard Codes Xn
Risk Statements 22
Safety Statements 26-36/37/39-22
WGK Germany 3
TSCA Yes
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesCatalyst for:
  • Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones
  • Highly selective rhodium-catalyzed hydrogenation reactions
  • Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes

Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes

Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Preparation Products And Raw materials
TRIS(2,4-DIMETHYLPHENYL)PHOSPHINE,Tris(2,4-dimethylphenyl)phosphine,98% TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE TRIS(3-METHOXYPHENYL)PHOSPHINE tris(2-fluorophenyl)phosphane Tris(4-fluorophenyl)phosphine DIPHENYL(O-TOLYL)PHOSPHINE TRIS(2,5-DIMETHYLPHENYL)PHOSPHINE Tris(2,3-dimethylphenyl)phosphine Tris(3,4-dimethylphenyl)phosphine dibromobis[tris(3,5-dimethylphenyl)phosphine]cobalt Tris(2,4-dimethylphenyl)phosphine-5,5',5''-trisulfonic acid trisodium salt, 97% TRIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINE TRI-M-TOLYLPHOSPHINE TRIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINE TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Phosphine (3,5-DIMETHYLPHENYL)PHOSPHINE Tris(2,6-dimethylphenyl)phosphine

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