N,N-Dimethylethylenediamine

N,N-Dimethylethylenediamine Basic information
Product Name:N,N-Dimethylethylenediamine
Synonyms:N,N-DIMETHYLETHYLENEDIAMINE(ASYM);RARECHEM AL BW 0045;ASYM-DIMETHYLETHYLENEDIAMINE;DIMETHYLAMINO ETHYLAMINE;DIMETHYLETHYLENEDIAMINE UNSYMMETRICAL;2-(Dimethylamino)ethylamine≥ 99% (GC);N,N-Dimethylethylenediamine >=98.0% (GC);1,2-EthanediaMine,N1,N1-diMethyl-
CAS:108-00-9
MF:C4H12N2
MW:88.15
EINECS:203-541-2
Product Categories:Polyamines;Organic Building Blocks;Nitrogen Compounds;Chemical Synthesis;Building Blocks;108-00-9
Mol File:108-00-9.mol
N,N-Dimethylethylenediamine Structure
N,N-Dimethylethylenediamine Chemical Properties
Melting point -70 °C
Boiling point 104-106 °C (lit.)
density 0.807 g/mL at 20 °C (lit.)
vapor pressure 0.35 psi ( 20 °C)
refractive index n20/D 1.438(lit.)
Fp 75 °F
storage temp. Store below +30°C.
form Liquid
pka9.59±0.10(Predicted)
color Clear colorless to pale yellow
PH11.4 (10g/l, H2O, 20℃)
explosive limit1.3-10.8%(V)
Water Solubility MISCIBLE
Sensitive Hygroscopic
BRN 605279
CAS DataBase Reference108-00-9(CAS DataBase Reference)
NIST Chemistry Reference1,2-Ethanediamine, N,N-dimethyl-(108-00-9)
EPA Substance Registry System1,2-Ethanediamine, N,N-dimethyl- (108-00-9)
Safety Information
Hazard Codes T+,F,C
Risk Statements 24/25-26-34-35-21/22-11-36/37-10
Safety Statements 26-28-36/37/39-45-36-28A-23-16
RIDADR UN 3302 6.1/PG 2
WGK Germany 2
RTECS KH8608250
8
Autoignition Temperature225 °C
Hazard Note Highly Flammable/Corrosive/Harmful
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29212900
ToxicityLD50 orally in Rabbit: 1135 mg/kg
MSDS Information
ProviderLanguage
2-Dimethylaminoethylamine English
SigmaAldrich English
ACROS English
ALFA English
N,N-Dimethylethylenediamine Usage And Synthesis
Chemical Propertiesclear colorless to pale yellow liquid
UsesN,N-Dimethylethylenediamine is a bidentate ligand that can be used:
  • To synthesize Schiff base ligands to prepare their zinc alkyl and zinc alkoxide complexes that initiate ring-opening polymerization of lactides.
  • As a ligand to prepare copper azido polymers.
  • In the synthesis of naphthalimides such as amonafide, an antitumor agent.
  • As the receptor in building fluorescent signaling systems to perturb the photoinduced intramolecular electron transfer (PET) process from the nitrogen lone-pair to the fluorophore.

UsesIt finds its application as an intermediate in the synthesis of Cefotiam. It is also used as a catalyst in the synthesis of allylic nitro compounds.
N,N'-Dimethyl-1,2-ethanediamine Bis(N-octadecyl-n-dimethyl)ethylenedi-ammonium bromide N,N-Diethylethylenediamine 1,2-Diaminopropane-N,N,N',N'-tetraacetic acid 1,4,8,11-TETRAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE 2-Aminoethyldiisopropylamine 2-(2-Aminoethylamino)ethanol 2-(Aminomethyl)-1-ethylpyrrolidine ETHYLENEDIAMINE-N,N'-DIACETIC-N,N'-DIPROPIONIC ACID TRIETHYLENETETRAMINE-N,N,N',N'',N''',N'''-HEXAACETIC ACID LABOTEST-BB LT00053078 N,N-Dimethylethylenediamine 1-(2-Aminoethyl)pyrrolidine 1,2-Cyclohexylenedinitrilotetraacetic acid Lysergic acid diethylamide N-(2-Hydroxyethyl)ethylenediaminetriacetic acid Creatinine N,N-DIMETHYLETHYLENEDIAMINE, (2-DIMETHYLAMINOETHYLAMINE)

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