Dodecyl 2-methylacrylate

Dodecyl 2-methylacrylate Basic information
Product Name:Dodecyl 2-methylacrylate
Synonyms:DODECYL 2-METHYL-2-PROPENOATE;DODECYL 2-METHYLPROPENOATE;METHACRYLIC ACID DODECYL ESTER;METHACRYLIC ACID N-DODECYL ESTER;METHACRYLIC ACID LAURYL ESTER;1-Dodecanol methacrylate;2-methyl-2-propenoicacidodecylester;dodecyl/pentadecylmethacrylate
CAS:142-90-5
MF:C16H30O2
MW:254.41
EINECS:205-570-6
Product Categories:Pyridines;Functional Monomer
Mol File:142-90-5.mol
Dodecyl 2-methylacrylate Structure
Dodecyl 2-methylacrylate Chemical Properties
Melting point -7 °C (lit.)
Boiling point 142 °C/4 mmHg (lit.)
density 0.868 g/mL at 25 °C (lit.)
vapor pressure 0.06Pa at 20℃
refractive index n20/D 1.445(lit.)
Fp >230 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
color Clear light yellow
Water Solubility insoluble
BRN 1708160
LogP6.68 at 20℃
CAS DataBase Reference142-90-5(CAS DataBase Reference)
NIST Chemistry Reference2-Propenoic acid, 2-methyl-, dodecyl ester(142-90-5)
EPA Substance Registry SystemLauryl methacrylate (142-90-5)
Safety Information
Hazard Codes Xi,N
Risk Statements 36/37/38-50/53
Safety Statements 26-28-60-61-28B
RIDADR UN 3082 9/PG 3
WGK Germany 2
RTECS OZ4300000
HazardClass 9
PackingGroup III
HS Code 29161490
Hazardous Substances Data142-90-5(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Dodecyl 2-methylacrylate English
SigmaAldrich English
ACROS English
Dodecyl 2-methylacrylate Usage And Synthesis
Chemical Propertiesclear colorless to yellowish liquid
UsesMiniemulsion polymerization of laurel methacrylate has been reported. Atom transfer radical polymerization and consecutive block copolymerization with methyl methacrylate has been investigated. Preparation of LMA based monolithic columns for CEC has been reported. LMA is used as a co-stabilizer to retard Ostwald ripening effect.
General DescriptionLiquid. Floats on water.
Reactivity ProfileDodecyl 2-methylacrylate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Tends to polymerize. Oxidizing and reducing agents may initiate polymerization. Reaction may also occur when heated [USCG, 1999].
Health HazardInhalation temporarily reduces blood pressure from 5 to 25%, increases respiratory rate, decreases heart rate, and causes some EKG changes. Liquid may cause irritation of eyes and skin. May be harmful if swallowed.
Fire HazardBehavior in Fire: Heat can induce polymerization with rapid release of energy. Sealed containers may rupture explosively.
Flammability and ExplosibilityNonflammable
Purification MethodsPurify the ester by fractional distillation in a high vacuum. Add 0.05% of hydroquinone monomethyl ether as stabilizer. [Rehberg & Fischer Ind Eng Chem 40 1430 1948, Beilstein 2 III 1290, 2 IV 1528.]
Dodecyl 2-methylacrylate Preparation Products And Raw materials
Dodecyl acrylate Methyl Oxybis(methyl-2,1-ethanediyl) diacrylate 7-HYDROXYCOUMARIN-3-CARBOXYLIC ACID OCTADECYL ESTER TRIDECYL METHACRYLATE VP/ACRYLATES/LAURYL METHACRYLATE COPOLYMER POLYMETHACRYLATE AESCINE DVB/ISOBORNYL METHACRYLATE/LAURYL METHACRYLATE COPOLYMER OCTADECYL METHACRYLATE Kresoxim-methyl Dodecyl 2-methylacrylate polymer n-Dodecyl alcohol, sulfated Dodecyl 2-methylacrylate Thiophanate-methyl VERATRINE 1H,1H,5H-OCTAFLUOROPENTYL METHACRYLATE METSULFURON METHYL

Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.