CHLORODIISOPROPYLPHOSPHINE

CHLORODIISOPROPYLPHOSPHINE Basic information
Product Name:CHLORODIISOPROPYLPHOSPHINE
Synonyms:AURORA KA-1318;CHLORODIISOPROPYLPHOSPHINE;DIISOPROPYLCHLOROPHOSPHINE;DIISOPROPYLPHOSPHINOUS CHLORIDE;DI-I-PROPYLCHLOROPHOSPHINE;Chlorodiiosopropylphosphine;Di-i-propylchlorophosphine,min.98%;CHLORODIISOPROPYLPHOSPHINE,96%
CAS:40244-90-4
MF:C6H14ClP
MW:152.6
EINECS:629-426-0
Product Categories:Achiral Phosphine;Alkyl Phosphine;P-Cl;organophosphine halide;Catalysis and Inorganic Chemistry;Phosphorus Compounds;Phosphorus Precursors;Ligand
Mol File:40244-90-4.mol
CHLORODIISOPROPYLPHOSPHINE Structure
CHLORODIISOPROPYLPHOSPHINE Chemical Properties
Boiling point 69 °C33 mm Hg(lit.)
density 0.959 g/mL at 25 °C(lit.)
refractive index n20/D 1.475(lit.)
Fp 39 °F
storage temp. Refrigerator
form Liquid
color Clear light yellow
Sensitive air sensitive, moisture sensitive
CAS DataBase Reference40244-90-4(CAS DataBase Reference)
Safety Information
Hazard Codes F,C
Risk Statements 11-34
Safety Statements 16-26-27-36/37/39-45-1
RIDADR UN 2924 3/PG 2
WGK Germany 3
HazardClass 3.1
PackingGroup II
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
CHLORODIISOPROPYLPHOSPHINE Usage And Synthesis
Chemical PropertiesColorless to light yellow liqui
UsesChlorodiisopropylphosphine can be used:
  • To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.
  • As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.
  • A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.

CHLORODIISOPROPYLPHOSPHINE Preparation Products And Raw materials
Preparation Products1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE-->(Diisopropylphosphino)(Diphenylphosphino)methane
DICHLOROBIS(CHLORODICYCLOHEXYLPHOSPHINE) PALLADIUM (II) DIBROMO(CHLORODI-T-BUTYLPHOSPHINE)PALLADIUM(II) DIMER Di-tert-butylchlorophosphane P-(1-METHYLETHYL)-P-(1,1-DIMETHYLETHYL)PHOSPHINOSELENOIC CHLORIDE TERT-BUTYLCYCLOHEXYLCHLOROPHOSPHINE DICYCLOHEXYLPHOSPHINYL CHLORIDE DICHLORO(CHLORODICYCLOHEXYLPHOSPHINE) PALLADIUM (II) DIMER AURORA KA-1182 DICHLORO(CHLORO-TERT-BUTYLCYCLOHEXYLPHOSPHINE) PALLADIUM (II) DIMER DICHLORO(CHLORODI-T-BUTYLPHOSPHINE)PALLADIUM(II) DIMER AURORA KA-1706 DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II) CHLORODICYCLOPENTYLPHOSPHINE DICHLOROBIS(CHLORO-T-BUTYLCYCLOHEXYLPHOSPHINE)PALLADIUM(II) DI-TERT-BUTYLCHLOROPHOSPHINE BORANE COMPLEX DI-1-ADAMANTYLPHOSPHINIC CHLORIDE DIBROMO(CHLORODI-TERT-BUTYLPHOSPHINE)PALLADIUM (II) DIMER P-CYCLOHEXYL-P-(1,1-DIMETHYLETHYL)PHOSPHINOSELENOIC CHLORIDE

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