N,N'-Diphenylformamidine

N,N'-Diphenylformamidine Basic information
Product Name:N,N'-Diphenylformamidine
Synonyms:LABOTEST-BB LTBB000577;N-(Phenyliminomethyl)aniline;N-Phenyl(anilinomethane)imine;N,N'-Diphenylformamidine,98%;N1,N2-diphenylformamidine;N,N'-diphenylformimidamide;N,N'-Diphenylformamidine;Formamidine, N,N'-diphenyl-
CAS:622-15-1
MF:C13H12N2
MW:196.25
EINECS:210-720-9
Product Categories:Aromatic Phenylacetic Acids and Derivatives;Imines/Amidines;Nitrogen Compounds;Organic Building Blocks
Mol File:622-15-1.mol
N,N'-Diphenylformamidine Structure
N,N'-Diphenylformamidine Chemical Properties
Melting point 136-139 °C(lit.)
Boiling point 323.14°C (rough estimate)
density 1.1265 (rough estimate)
refractive index 1.5014 (estimate)
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Crystalline Powder or Crystals
pka7.70±0.10(Predicted)
color White to yellow to beige
Sensitive Moisture Sensitive
BRN 511953
CAS DataBase Reference622-15-1(CAS DataBase Reference)
NIST Chemistry ReferenceN,n'-diphenylformamidine(622-15-1)
EPA Substance Registry SystemN,N'-Diphenylformamidine (622-15-1)
Safety Information
Hazard Codes Xn
Risk Statements 22
Safety Statements 22-24/25
WGK Germany 3
RTECS PB7705000
10-21
TSCA Yes
HS Code 29215900
MSDS Information
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N,N'-Diphenylformamidine Usage And Synthesis
Chemical Propertieswhite to yellowish crystals or cryst. powder
UsesN,N′-Diphenylformamidine was used in the microwave-assisted synthesis of 5-aminopyrazol-4-yl ketones. It was also used in the preparation of monomethine dyes containing imide functional groups.
UsesN,N''-Diphenylformamidine is used in the preparation of polyfluoro benzoxazole polymethine dyes which are used as fluorescent labels for biomolecules.
Synthesis Reference(s)Journal of the American Chemical Society, 76, p. 3978, 1954 DOI: 10.1021/ja01644a034
General DescriptionN,N′-Diphenylformamidine is an N,N-disubstituted formamide and it forms adducts with phosgeneand oxalyl chloride.
Purification MethodsThe hydrate is obtained from aqueous EtOH. [Beilstein 12 H 236, 12 IV 372.]
N,N'-Diphenylformamidine Preparation Products And Raw materials
3-(3,4-DICHLOROPHENYL)-N-(4-METHOXYPHENYL)-[1,2,4]TRIAZOLO[4,3-C]QUINAZOLIN-5-AMINE 3-(2,4-DICHLOROPHENYL)-N-(4-METHOXYPHENYL)[1,2,4]TRIAZOLO[4,3-C]QUINAZOLIN-5-AMINE 3-(4-BROMOPHENYL)-N-PHENYL[1,2,4]TRIAZOLO[4,3-C]QUINAZOLIN-5-AMINE 3-(4-BROMOPHENYL)-N-(4-METHOXYPHENYL)[1,2,4]TRIAZOLO[4,3-C]QUINAZOLIN-5-AMINE 2-(3-CHLOROANILINO)-4H-3,1-BENZOXAZIN-4-ONE N1-(2-METHYL-3-NITROPHENYL)-N1-([(2-METHYL-3-NITROPHENYL)IMINO]METHYL)-2-NITROBENZENE-1-SULFONAMIDE Dibenzoyltartaric acid 6-CHLORO-2-[3-(TRIFLUOROMETHYL)ANILINO]-4H-3,1-BENZOXAZIN-4-ONE HOLOCALIN(P) 2-[3-(trifluoromethyl)anilino]-4H-3,1-benzoxazin-4-one (4,5-DIMETHYL-3-PHENYL-3H-THIAZOL-2-YLIDENE)-PHENYL-AMINE 3-(2,4-DICHLOROPHENYL)-N-PHENYL[1,2,4]TRIAZOLO[4,3-C]QUINAZOLIN-5-AMINE 2-Anilino-4H-3,1-benzoxazin-4-one HOLOCAINE HYDROCHLORIDE 4-CHLORO-3-(4-CHLOROPHENYL)-2-[(4-CHLOROPHENYL)IMINO]-1,3-THIAZOLAN-5-ONE 3-(2-FLUOROPHENYL)-N-(4-METHOXYPHENYL)[1,2,4]TRIAZOLO[4,3-C]QUINAZOLIN-5-AMINE BENZAMIDINE 3-(2-FLUOROPHENYL)-N-PHENYL[1,2,4]TRIAZOLO[4,3-C]QUINAZOLIN-5-AMINE

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