Sodium methanesulfinate

Sodium methanesulfinate Basic information
Description
Product Name:Sodium methanesulfinate
Synonyms:Sodium methanesulfinate,Methanesulfinic acid sodium salt;Sodium methanesulphinate, tech;Methanesulfinic acid,sodiuM salt (1:1);Sodium methanesulphinate Methanesulfinic acid sodium salt;Sodium methanesulfinate technical grade, 85%;METHANESULPHINIC ACID SODIUM SALT;SODIUM METHANESULFINATE;sodium methanesulphinate
CAS:20277-69-4
MF:CH5NaO2S
MW:104.1
EINECS:243-669-6
Product Categories:Aliphatics
Mol File:20277-69-4.mol
Sodium methanesulfinate Structure
Sodium methanesulfinate Chemical Properties
Melting point 222-226 °C (dec.) (lit.)
storage temp. Inert atmosphere,Room Temperature
solubility Methanol, Water (Slightly)
form Powder
color White to light beige
Water Solubility soluble
Sensitive Air Sensitive & Hygroscopic
BRN 3565430
Stability:Hygroscopic
InChIKeyLYPGDCWPTHTUDO-UHFFFAOYSA-M
CAS DataBase Reference20277-69-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 22-20/21/22
Safety Statements 36/37-24/25
RIDADR 2811
WGK Germany 3
PackingGroup III
HS Code 29309090
MSDS Information
ProviderLanguage
Methanesulfinic acid sodium salt English
SigmaAldrich English
ACROS English
ALFA English
Sodium methanesulfinate Usage And Synthesis
DescriptionSodium methanesulfinate is an aliphatic sodium sulfinate. Conjugate addition of sodium methanesulfinate to vinyl heterocycles has been described. Cross-coupling reaction between aryl boronic acid and sodium methanesulfinate has been studied. It can be used in the preparation of alkyl methyl sulfone and methyl bis(4-tolyl)sulfoniumtrifluoromethanesulfonate. It is also employed in the synthesis of two sulfonyl type reversible addition-fragmentation transfer (RAFT) agents such as benzyl methylsulfonyldithioformate and benzyl phenylsulfonyldithioformate. Moreover, it can be used for synthesizing cyclooxygenase-2 inhibitors.
Chemical PropertiesWhite to light beige powder
UsesSodium methylsulfinate can be used to synthesize cyclooxygenase-2 inhibitors.
General DescriptionSodium methanesulfinate is an aliphatic sodium sulfinate. Conjugate addition of sodium methanesulfinate to vinyl heterocycles has been described. Cross-coupling reaction between aryl boronic acid and sodium methanesulfinate has been studied. Its stock solution was prepared from methanesulfonic acid by adding one equivalent of sodium hydroxide and diluting it to 4M.
ACID VIOLET 34 ACID BLUE 41 Sodium anthraquinone-2-sulfonate REACTIVE BLACK 5 sodium Acid Green 25 Antirust agent T702 ACID BLUE 80 Sodium methanesulfinate Sodium citrate Sodium p-toluenesulfinate ACID BLUE 25 2-METHYL-2-PROPENE-1-SULFONIC ACID SODIUM SALT Molasses Sodium lignosulfonate ACID BLUE 40 8-CHLOROADENOSINE-3',5'-CYCLIC MONOPHOSPHOROTHIOATE, RP-ISOMER SODIUM SALT ACID GREEN 27 (C.I. 61580)

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