Chloromethyltrimethylsilane

Chloromethyltrimethylsilane Basic information
Product Name:Chloromethyltrimethylsilane
Synonyms:CHLOROMETHYLTRIMETHYLSILANE;Chloromethyltrimethylsilane, 98+%;chlormethyl-trimethyl-silane;Chloro(trimethylsilyl)methane;ChloroMethyltriMethylsilane, 98+% 100GR;ChloroMethyltriMethylsilane, 98+% 25GR;(CHLOROMETHYL)TRIMETHYLSILANE FOR SYNTHE;ChloroMethyltriMethylsilane, 97%, SpcSeal
CAS:2344-80-1
MF:C4H11ClSi
MW:122.67
EINECS:219-058-5
Product Categories:pharmacetical;Halides;Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Chemical Synthesis;Organometallic Reagents;Organosilicon;Others;bc0001
Mol File:2344-80-1.mol
Chloromethyltrimethylsilane Structure
Chloromethyltrimethylsilane Chemical Properties
Melting point <0°C
Boiling point 98-99 °C(lit.)
density 0.88 g/mL at 20 °C
vapor pressure ~25 mm Hg ( 20 °C)
refractive index n20/D 1.418(lit.)
Fp 27 °F
storage temp. Store below +30°C.
solubility soluble in Benzene, Methanol
form Liquid
Specific Gravity0.879
color Clear colorless
Water Solubility insoluble
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Sensitive Moisture Sensitive
BRN 906705
CAS DataBase Reference2344-80-1(CAS DataBase Reference)
NIST Chemistry ReferenceSilane, (chloromethyl)trimethyl-(2344-80-1)
EPA Substance Registry SystemSilane, (chloromethyl)trimethyl- (2344-80-1)
Safety Information
Hazard Codes F,Xi,C
Risk Statements 11-36/37/38-34
Safety Statements 16-26-36-29-37/39-33
RIDADR UN 1993 3/PG 2
WGK Germany 3
10-21
Hazard Note Irritant/Highly Flammable
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29310095
MSDS Information
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Chloromethyltrimethylsilane Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS LIQUID
Uses(Chloromethyl)trimethylsilane can be treated with aldehydes or ketones in the presence of triphenylphosphine to synthesize terminal alkenes. It can also be used in the preparation of a reagent, trimethylsilylmethyl magnesium chloride, commonly used in Peterson methylenation.
Uses(Chloromethyl)trimethylsilane is used for Wittig reaction and building blocks.
Chloromethyltrimethoxysilane 1-CHLOROETHYLTRIMETHYLSILANE TRIMETHYLSILANE CHLOROMETHYLDODECYLDIMETHYLSILANE (Trifluoromethyl)trimethylsilane DIMETHYLTHEXYLSILYL CHLORIDE ALLYL(CHLOROMETHYL)DIMETHYLSILANE tert-Butyldimethylsilyl chloride 1-CHLOROVINYLTRIMETHYLSILANE (DICHLOROMETHYL)TRIMETHYLSILANE (TRICHLOROMETHYL)TRIMETHYLSILANE (DICHLOROMETHYL)DIMETHYL-N-PROPYLSILANE CHLOROMETHYLDIMETHYL-N-BUTYLSILANE BIS(TRIMETHYLSILYL)CHLOROMETHANE BIS(CHLOROMETHYL)DIMETHYLSILANE (TRIMETHYLSILYLMETHYL)DIMETHYLCHLOROMETHYLSILANE CHLOROMETHYLDIMETHYLPHENYLSILANE (Chloromethyl)dimethylethylsilane

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