ChemicalBook Product Catalog Chemical Reagents Organic reagents Borate 2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL

2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL

2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL Basic information
Product Name:2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL
Synonyms:2-(Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol;2-HYDROXYBENZENEBORONIC ACID, PINACOL ESTER;2-HYDROXYPHENYLBORONIC ACID, PINACOL CYCLIC ESTER;2-HYDROXYPHENYLBORONIC ACID, PINACOL ESTER;2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL;2-(2-HYDROXYPHENYL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol,min.97%;2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL, MIN. 97%
CAS:269409-97-4
MF:C12H17BO3
MW:220.07
EINECS:
Product Categories:Boronic Acids and Derivatives;Chemical Synthesis;Organometallic Reagents;Aryl Boronate Esters;Boronate Esters;organic or inorganic borate;Boronic acids;B (Classes of Boron Compounds);Boronic Acids Esters
Mol File:269409-97-4.mol
2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL Structure
2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL Chemical Properties
Boiling point 282 °C(lit.)
density 1.05 g/mL at 25 °C(lit.)
refractive index n20/D 1.506(lit.)
Fp 230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
Water Solubility Insoluble in water
form liquid
pka10.17±0.35(Predicted)
color pale yellow
CAS DataBase Reference269409-97-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-22
Safety Statements 26-36
WGK Germany 3
Hazard Note Irritant
TSCA No
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL Usage And Synthesis
Chemical Propertiespale yellow to brown liquid
UsesReactant involved in:
  • Synthesis of indolo-fused heterocyclic inhibitors of polymerase enzyme of hepatitis C
  • Studies of pi-interactions, electronic structure and transient UV absorption of subphthalocyanine-borate-bridged ferrocene-fullerene conjugates
  • Synthesis of subphthalocyanine and fused-ring nicotine derivatives
  • Suzuki-Miyaura coupling-triflation sequence, reduction and salt formation for synthesis of hydroxylated oligoarene phosphines
Uses2-(4,4,5,5-TetraMethyl-1,3,2-dioxaborolan-2-yl)phenol can be widely used in Suzuki coupling chemistry.
2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL Preparation Products And Raw materials
2-FLUORO-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL 2-TERT-BUTOXYCARBONYLOXYPHENYLBORONIC ACID, PINACOL ESTER 2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENYL ACETATE 2-HYDROXY-5-METHOXYCARBONYLPHENYLBORONIC ACID, PINACOL ESTER 2-(TRIFLUOROMETHOXY)PHENYLBORONIC ACID, PINACOL ESTER 4-METHOXY-2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL 2-BENZYLOXYPHENYLBORONIC ACID, PINACOL ESTER 2-METHOXY-5-METHOXYCARBONYLPHENYLBORONIC ACID, PINACOL ESTER [2-(4,4,5,5-Tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenoxy]-acetonitrile 2,4-DIMETHOXYPHENYLBORONIC ACID, PINACOL ESTER 2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL 3-METHOXY-5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL 3,5-DIFLUORO-2-METHOXYPHENYLBORONIC ACID, PINACOL ESTER 2-METHOXYPHENYLBORONIC ACID PINACOL ESTER 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-4-(trifluoromethylsulfonyl)phenol 2-(5-[1,3]DIOXOLAN-2-YL-2,4-DIMETHOXY-PHENYL)-BORONIC ACID PINACOL ESTER 4,4,5,5-TETRAMETHYL-2-[2-(2,2,2-TRIFLUORO-ETHOXY)-PHENYL]-[1,3,2]DIOXABOROLANE 2-[2-([1,3]DIOXOLAN-2-YLMETHOXY)-PHENYL]-4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLANE
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