ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organomagnesium Cyclopropylmagnesium bromide

Cyclopropylmagnesium bromide

Cyclopropylmagnesium bromide Basic information
Product Name:Cyclopropylmagnesium bromide
Synonyms:Cyclopropylmagnesium bromide solution( 1.0 M solution in THF);Cyclopropylmagnesium bromide solution( 0.5 M solution in THF);Bromocyclopropylmagnesium;Cyclopropylbromomagnesium;Cyclopropylmagnesium bromide, ca 0.5M in THF;Cyclopropylmagnesium Bromide (15% in Tetrahydrofuran, ca. 1mol/L);cyclopropylmagnesium bromide solution;Cyclopropylmagnesium bromide,0.5M solution inTHF
CAS:23719-80-4
MF:C3H5BrMg
MW:145.28
EINECS:472-500-0
Product Categories:Grignard Reagent;25mL Sure/Seal Reagents;Cyclopropanes;Grignard Reagents;Chemical Synthesis;Organometallic Reagents;Grignard Reagents & Alkyl Metals;Simple 3-Membered Ring Compounds;Synthetic Organic Chemistry;Alkyl;Grignard Reagents;Organometallic Reagents
Mol File:23719-80-4.mol
Cyclopropylmagnesium bromide Structure
Cyclopropylmagnesium bromide Chemical Properties
Boiling point 65 °C
density 0.968 g/mL at 25 °C
Fp 65°C
storage temp. 2-8°C
form Turbid Liquid
color Yellow to green
Water Solubility Soluble in water (17 mg/ml), (25°C). Soluble in organic solvents.
Sensitive Air & Moisture Sensitive
InChIKeyQUPLLJGAJVXXBW-UHFFFAOYSA-M
CAS DataBase Reference23719-80-4(CAS DataBase Reference)
Safety Information
Hazard Codes F,Xi,C
Risk Statements 11-14-19-36/37/38-40-37-34
Safety Statements 16-26-45-36/37/39
RIDADR UN 3399 4.3/PG 2
WGK Germany 1
HazardClass 4.3
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
Cyclopropylmagnesium bromide Usage And Synthesis
Chemical PropertiesClear colorless solution
UsesIt often acts as the starting nutrient mix for dropout studies where fermentation conditions required the absence of one or more essential amino acids. For classifying Yeasts based on colonial characteristics and cell morphology.
UsesCyclopropylmagnesium bromide solution has been used in Grignard reaction that finds application as the key step in the preparation of aminopropylindenes, a chemotype of oxidosqualene cyclase (OSC) inhibitors from Grundmann′s ketone. It can react with trimethylborate to form cyclopropylboronic acid, which can undergo Suzuki-type coupling reactions with different aryl, and heteroaryl bromides to form the cyclopropyl adducts.
UsesGrignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
General DescriptionThis product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.
Cyclopropylmagnesium bromide Preparation Products And Raw materials
Preparation Products4-(4-cyclopropylnaphthalen-1-yl)-1H-1,2,4-triazole-5(4H)-thione-->Cyclopropyl 2-fluorobenzyl ketone-->4-cyclopropylanisole-->3-Cyclopropyl-benzeneboronic acid -->5-cyclopropylnicotinonitrile-->(4-Chloro-2-fluorophenyl)(cyclopropyl)methanol-->Cyclopropyl(2-fluorophenyl)methanol-->Cyclopropyl (2-chlorophenyl)methanol-->(3-BROMOPHENYL)(CYCLOPROPYL)METHANAMINE-->Carbamic acid, [(1S)-1-(cyclopropylcarbonyl)-2-methylpropyl]-, 1,1-dimethylethyl ester (9CI)-->Cyclopropyl(4-pyridyl) ketone
Cyclopropyl methyl ketone Cyclopropyl acetylene Rocuronium bromide ETHYNYLMAGNESIUM BROMIDE Methylmagnesium Bromide N-PROPYLMAGNESIUM BROMIDE ISOPROPYLMAGNESIUM BROMIDE Sodium bromate Cyclopropylmagnesium bromide Cyclopropanesulfonyl chloride Allyl bromide Cyclopropyl bromide Ethylmagnesium bromide Dicyclopropane methylamine Cyclopropanecarbonitrile Methyl bromide Propylthiouracil Allyl chloride
Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.