N-METHYLBUTYLAMINE

N-METHYLBUTYLAMINE Basic information
Product Name:N-METHYLBUTYLAMINE
Synonyms:N-N-BUTYLMETHYLAMINE;N-Methyl-1-butaneamine;N-Methyl-1-butylamine;N-Methylbutylamine,98%;1-Butanamine,N-methyl-;Butylamine, N-methyl-;Butylamine,N-methyl-;Butylmethylamine
CAS:110-68-9
MF:C5H13N
MW:87.16
EINECS:203-791-2
Product Categories:
Mol File:110-68-9.mol
N-METHYLBUTYLAMINE Structure
N-METHYLBUTYLAMINE Chemical Properties
Melting point -75 °C
Boiling point 90.5-91.5 °C(lit.)
density 0.736 g/mL at 25 °C(lit.)
refractive index n20/D 1.3995(lit.)
Fp 35 °F
storage temp. Store below +30°C.
pkapK1: 10.90(+1) (25°C)
form clear liquid
color Colorless to Light orange to Yellow
explosive limit1.3%(V)
BRN 1209231
CAS DataBase Reference110-68-9(CAS DataBase Reference)
EPA Substance Registry System1-Butanamine, N-methyl- (110-68-9)
Safety Information
Hazard Codes F,C
Risk Statements 11-20/21/22-34
Safety Statements 16-26-36/37/39-45
RIDADR UN 2945 3/PG 2
WGK Germany 3
RTECS EO5250000
HazardClass 3
PackingGroup II
HS Code 29211999
Hazardous Substances Data110-68-9(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 420 mg/kg LD50 dermal Rabbit 932 mg/kg
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
N-METHYLBUTYLAMINE Usage And Synthesis
Chemical PropertiesButyl amines are highly flammable, colorless liquids (n-turns yellow on standing) with ammoniacal or fishlike odors. n-isomer:
Chemical PropertiesCLEAR COLOURLESS LIQUID
UsesIntermediate.
DefinitionChEBI: A secondary aliphatic amine having methyl and n-butyl as the two alkyl groups.
General DescriptionA water-white liquid with an ammonia-like odor. Density 0.736 g / cm3 and flash point 35°F (Aldrich) .Vapors heavier than air. Used to make other chemicals.
Air & Water ReactionsHighly flammable. Slightly soluble in water.
Reactivity ProfileN-METHYLBUTYLAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
HazardFlammable, dangerous fire risk.
Health HazardMay cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire HazardFlammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety ProfilePoison by intravenous route. Moderately toxic by ingestion, skin contact, and intraperitoneal routes. Mildly toxic by inhalation. A skin and severe eye irritant. Flammable liquid when exposed to heat, sparks, or flame. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
Potential ExposureAlert: (n-isomer): Possible risk of forming tumors, suspected of causing genetic defects, suspected reprotoxic hazard, Primary irritant (w/o allergic reaction), (sec-isomer): Drug. n-Butylamine is used in pharmaceuticals; dyestuffs, rubber, chemicals, emulsifying agents; photography, desizing agents for textiles; pesticides, and synthetic agents. sec-Butylamine is used as a fungistate. tert-Butylamine is used as a chemical intermediate in the production of tert-Butylaminoethyl methacrylate (a lube oil additive); as an intermediate in the production of rubber and in rust preventatives and emulsion deterrents in petroleum products. It is used in the manufacture of several drugs
ShippingUN1125 n-Butylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material. UN2014 Isobutylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material
IncompatibilitiesMay form explosive mixture with air. May accumulate static electrical charges, and may causeignition of its vapors. n-Butylamine is a weak base; reacts with strong oxidizers and acids, causing fire and explosion hazard. Incompatible with organic anhydrides; isocyanates, vinyl acetate; acrylates, substituted allyls; alkylene oxides; epichlorohydrin, ketones, aldehydes, alcohols, glycols, phenols, cresols, caprolactum solution. Attacks some metals in presence of moisture. The tert-isomer will attack some forms of plastics
Waste DisposalUse a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner andscrubber. All federal, state, and local environmental regulations must be observed.
N-METHYLBUTYLAMINE Preparation Products And Raw materials
Raw materialsN,N-Dimethylaminobutane-->Methanol-->Formic acid-->Butylamine
Preparation ProductsLEUCOMALACHITE GREEN-->Tributylamine-->N-(2-bromobenzyl)-N-butyl-N-methylamine
N-ACETYL-L-PHENYLALANYL-3,5-DIIODO-L-TYROSINE 4'-Chloroacetoacetanilide OIL BLUE N N,N'-OCTAMETHYLENEBIS(DICHLOROACETAMIDE) H-GAMMA-GLU-GLU-OH N-NITROSO-METHYLBUTYLAMINE dimethyl-2-methylbutylamine 1-[1-(4-CHLOROPHENYL)CYCLOBUTYL]-3-METHYLBUTYLAMINE 2-[(4-CHLORO-1-NAPHTHYL)OXY]-3-METHYLBUTYLAMINE 1-[1-(4-chlorophenyl) cyclobutyl]-3-methylbutylamine citrate 4-(BUTYLAMINO)BENZOIC ACID 2-(4-CHLORO-3-METHYLPHENOXY)-3-METHYLBUTYLAMINE GLUTATHIONE REDUCED, IMMOBILIZED ON AGAROSE CL-4B N-Propylcyclopropanemethylamine H-GAMMA-GLU-PHE-OH (N-BUTYLAMINO)ACETONITRILE N6-Cbz-L-Lysine 1-(3,4-DIHYDRO-2-NAPHTHYL)PYRROLIDINE

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