Cobalt naphthenate

Cobalt naphthenate Basic information
Product Name:Cobalt naphthenate
Synonyms:Cobalt naphthenate, in mineral spirits (6% Co);Cobalt naphthenate[powdery];Cobalt Naphthenate Liquid;Cobalt naphthenate, 10.0% Co;Cobalt naphthenate solution, 50 wt. % in mineral spirits;cobaltnaphthenate(powder);cobaltnaphthenates,powder;Cobalt naphthenate, 8% Co
CAS:61789-51-3
MF:C22H16CoO4
MW:403.29324
EINECS:263-064-0
Product Categories:UVCBs-organic-metal salts;metal carboxylate;Classes of Metal Compounds;Co (Cobalt) Compounds;Transition Metal Compounds;C;Polymer Additives;Polymer Science;Polymerization and Polymer Property Modifiers;Catalysis and Inorganic Chemistry;Chemical Synthesis;Cobalt;Stains and Dyes;Stains&Dyes, A to;Rubber Chemicals
Mol File:61789-51-3.mol
Cobalt naphthenate Structure
Cobalt naphthenate Chemical Properties
Melting point <-7℃
density 0.921 g/mL at 25 °C
vapor pressure 0Pa at 20℃
refractive index n20/D 1.4620
Fp 120 °F
storage temp. 2-8°C
form liquid
color dark
Specific Gravity0.95
Water Solubility Insoluble in water.
EPA Substance Registry SystemCobalt naphthenate (61789-51-3)
Safety Information
Hazard Codes Xn,N,T
Risk Statements 49-10-36/38-42/43-50/53-40-65
Safety Statements 53-23-45-60-61-36/37-62
RIDADR UN 1993 3/PG 3
WGK Germany 3
RTECS QK8925000
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29319090
MSDS Information
ProviderLanguage
Cobalt naphthenate English
SigmaAldrich English
ALFA English
Cobalt naphthenate Usage And Synthesis
Chemical PropertiesBlack liquid
Chemical PropertiesCobalt naphthenate is a flammable brown powder or bluish-red solid; freezing/melting point = 140°C; flash point = 49°C; autoignition temperature = 276°C. Hazard identification (based on NFPA-704 M Rating System): Health 1, flammability 2, reactivity 0. Insoluble in water.
UsesCobalt naphthenate is widely used in polyester resins and paint driers. It is used as a curing accelerator, cross linker catalyst for unsaturated polyester resins. It is also used in the production of adhesives, varnishes and waterproofing agents for textiles. Further, it is used as corrosion inhibitors, lubricants, and fuel additives. It plays an important role as oil drying agents.
UsesCobalt naphthenate may be used as a catalyst that facilitates the free radical polymerization of (3-methacryloxypropyl)trimethoxysilane (MPS), which can be used to functionalize alumina nanoparticles. It can be used as a promoter for the development of unsaturated flame retardant polyesters.
General DescriptionCobalt naphthenate is a brown powder or a bluish-red solid. Cobalt naphthenate is easily ignited and once ignited can burn profusely. Cobalt naphthenate is used to make paints and varnish.
Air & Water ReactionsHighly flammable.
Reactivity ProfileCOBALT NAPHTHENATE has weak oxidizing or reducing powers. Redox reactions can however still occur. The majority of compounds in this class are slightly soluble or insoluble in water. If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic. These compounds are not water-reactive.
Health HazardFire may produce irritating and/or toxic gases. Contact may cause burns to skin and eyes. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
Fire HazardFlammable/combustible material. May be ignited by friction, heat, sparks or flames. Some may burn rapidly with flare burning effect. Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with explosive violence. Substance may be transported in a molten form at a temperature that may be above its flash point. May re-ignite after fire is extinguished.
Flammability and ExplosibilityNotclassified
Contact allergensCobalt naphthenate is made by treating cobalt hydroxide or acetate with naphthenic acid. It is an accelerant in rubber, unsaturated polyester, and vinyl ester resins.
Safety ProfileModerately toxic by ingestion. Flammable when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes.
Potential ExposureCobalt naphthenate is used as a drying agent in paints, varnishes; inks, and for curing plastics.
ShippingUN2001 Cobalt naphthenate powder, Hazard Class: 4.1; Labels: 4.1-Flammable solid. UN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required
IncompatibilitiesHighly flammable; powder or dust can form an explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
NAPHTHENIC ACID NAPHTHENIC ACID SODIUM SALT Aluminum acetylacetonate N-BUTYLISOCYANIDE DICHLORO(ETHYLENEDIAMINE)PLATINUM(II) Barium naphthenate 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE Tosylmethyl isocyanide COBALT(II) ACETYLACETONATE COBALT BLUE Ethyl isocyanoacetate Cobalt decanoate TERT-BUTYL ISOCYANIDE Cobalt chloride COBALT ETHYLENE DIAMINE CHLORIDE Benzyl isocyanide Cobalt Naphthenic acids, lithium salts

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