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| | Ferrocenecarboxaldehyde Basic information |
| | Ferrocenecarboxaldehyde Chemical Properties |
| Melting point | 118-120 °C (lit.) | | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | | form | Crystalline Powder or Crystals or Crystals | | color | Orange to red to brown | | Water Solubility | INSOLUBLE | | Sensitive | Air Sensitive | | λmax | 314nm(DMF aq.)(lit.) | | Exposure limits | ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3 | | Stability: | Stable. Incompatible with strong oxidizing agents. | | EPA Substance Registry System | Ferrocenecarboxaldehyde (12093-10-6) |
| Safety Statements | 22-24/25 | | WGK Germany | 3 | | TSCA | Yes | | HS Code | 29319090 |
| | Ferrocenecarboxaldehyde Usage And Synthesis |
| Chemical Properties | crystalline solid | | Uses | Ferrocenecarboxaldehyde, is used to prepare chiral ferrocene aziridinylmethanols for selective azomethine ylide cycloaddtion. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals. | | Purification Methods | It forms red crystals from heptane/CH2Cl2, EtOH or pet ether and sublimes at 70o/1mm. The cyanohydrin has m 104o (from *C6H6/EtOH). The semicarbazone has m 217-219o(dec) after recrystallisation from aqueous EtOH. The oxime provides two isomers from pet ether viz m 96-99o and m 155o. The O-acetyloxime has m 80-81o after recrystallisation from hexane [Lindsay & Hauser J Org Chem 22 355 1957]. The 2,4-dinitrophenylhydrazone has m 248o(dec). [Beilstein 16 IV 1798, Graham et al. J Am Chem Soc 79 3416 1957, Broadhead et al. J Chem Soc 650 1958.] |
| | Ferrocenecarboxaldehyde Preparation Products And Raw materials |
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