(TERT-BUTYLDIMETHYLSILYLOXY)ACETALDEHYDE

(TERT-BUTYLDIMETHYLSILYLOXY)ACETALDEHYDE Basic information
Product Name:(TERT-BUTYLDIMETHYLSILYLOXY)ACETALDEHYDE
Synonyms:(tert-ButyldiMethylsilyloxy)acetaldehyde;(tert-ButyldiMethylsilyloxy)acetaldehyde 90%;(tert-Butyldimethylsiloxy)acetaldehyde,90%;Acetaldehyde,2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-;(tert-Butyl-dimethyl-silanyloxy)-acetaldehyde;2-(Tert-Butyldimethylsiloxy)acetaldehyde;(TERT-BUTYLDIMETHYLSILYLOXY)ACETALDEHYDE;T-BUTYLDIMETHYLSILOXYACETALDEHYDE
CAS:102191-92-4
MF:C8H18O2Si
MW:174.31
EINECS:
Product Categories:Pyridines ,Halogenated Heterocycles;Aldehydes;C8;Carbonyl Compounds
Mol File:102191-92-4.mol
(TERT-BUTYLDIMETHYLSILYLOXY)ACETALDEHYDE Structure
(TERT-BUTYLDIMETHYLSILYLOXY)ACETALDEHYDE Chemical Properties
Melting point 165-167 ºC
Boiling point 165-167 °C(lit.)
density 0.915 g/mL at 25 °C(lit.)
refractive index n20/D 1.432(lit.)
Fp 140 °F
storage temp. 2-8°C
form Powder
color White to light beige to grey
Specific Gravity0.915
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
InChIInChI=1S/C8H18O2Si/c1-8(2,3)11(4,5)10-7-6-9/h6H,7H2,1-5H3
InChIKeyMEBFFOKESLAUSJ-UHFFFAOYSA-N
SMILESC(=O)CO[Si](C(C)(C)C)(C)C
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR UN 1989 3/PG 3
WGK Germany 3
TSCA No
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
(TERT-BUTYLDIMETHYLSILYLOXY)ACETALDEHYDE Usage And Synthesis
Chemical PropertiesClear colorless to straw colored liquid
UsesEmployed in the construction of the key tetrahydropyran subunit in a recent synthesis of the marine natural product (–)-dactylodide.
(TERT-BUTYLDIMETHYLSILYLOXY)ACETALDEHYDE Preparation Products And Raw materials
Preparation Products(S,E)-N-(2-(tert-butyldimethylsilyloxy)ethylidene)-2-methylpropane-2-sulfinamide-->(E)-4-[[(1,1-DiMethylethyl)diMethylsilyl]oxy]-2-butenoic Acid Ethyl Ester
3-TRIMETHYLSILYLPROPYNAL 2-(ALLYLDIMETHYLSILYL)PYRIDINE (-)-(3S)-3-([TERT-BUTYL(DIMETHYL)SILYL]OXY)DIHYDROFURAN-2(3H)-ONE THYMIDINE GLYCOL CEP (S)-3-(TERT-BUTYLDIMETHYLSILYLOXY)PIPERIDIN-2-ONE AKOS 91264 ETHYL (S)-(-)-2-(TERT-BUTYLDIMETHYLSILYLOXY)PROPIONATE (TERT-BUTYLDIMETHYLSILYLOXY)ACETALDEHYDE (+)-(3R)-3-[(TERT-BUTYL(DIMETHYL)SILYL)OXY]DIHYDROFURAN-2(3H)-ONE (-)-(3S)-3-([TERT-BUTYL(DIMETHYL)SILYL]OXY)-5-HYDROXYPENTAN-2-ONE 2-(TERT-BUTYL-DIMETHYL-SILANYLOXY)-PROPIONALDEHYDE Ethyl [(tert-Butyldimethylsilyl)oxy]acetate 2-(tert-Butyl-dimethylsilanyloxy)-1-(4-fluorophenyl)-ethanone 1-(TERT-BUTYLDIMETHYLSILYLOXY)-2-PROPANONE 2-(TERT-BUTYLDIMETHYLSILYLOXY)CYCLOHEXA& (6S)-2-BENZYL-6-(TERT-BUTYLDIMETHYLSILYLOXY)CYCLOHEXANONE RARECHEM AL BE 0828

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