ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatic acids mono-Methyl terephthalate

mono-Methyl terephthalate

mono-Methyl terephthalate Basic information
Description References
Product Name:mono-Methyl terephthalate
Synonyms:Monomethyl ester;Tetraphthalic acid;Mmt(Mono-MethylTerephthalate);Mono-methyl terephthalate (MMT);m-Methyl terephthalate ,97%;Mono-methyl terephth;mono-Methyl terephthalate, Methyl 4-carboxybenzoate;M-Methyl terephthalate
CAS:1679-64-7
MF:C9H8O4
MW:180.16
EINECS:216-849-7
Product Categories:Aromatic Esters;Phthalic Acids, Esters and Derivatives;Carboxylic Acids;Phenyls & Phenyl-Het;Heterocyclic Compounds;Carboxylic Acids;Phenyls & Phenyl-Het;C8 to C9;Carbonyl Compounds;Esters
Mol File:1679-64-7.mol
mono-Methyl terephthalate Structure
mono-Methyl terephthalate Chemical Properties
Melting point 220-223 °C (lit.)
Boiling point 232.96°C (rough estimate)
density 1.1987 (rough estimate)
refractive index 1.4209 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility chloroform/methanol: soluble50mg/mL, clear, colorless (1:1)
pka3.77±0.10(Predicted)
form Powder
color White to off-white
Water Solubility Slightly soluble in water. Also soluble in methanol, benzene and ether.
BRN 1911082
InChIKeyREIDAMBAPLIATC-UHFFFAOYSA-N
CAS DataBase Reference1679-64-7(CAS DataBase Reference)
NIST Chemistry ReferenceMonomethyl terephthalate(1679-64-7)
EPA Substance Registry System1,4-Benzenedicarboxylic acid, monomethyl ester (1679-64-7)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
TSCA Yes
HazardClass IRRITANT
HS Code 29173980
Hazardous Substances Data1679-64-7(Hazardous Substances Data)
MSDS Information
ProviderLanguage
1,4-Benzenedicarboxylic acid monomethyl ester English
SigmaAldrich English
ACROS English
mono-Methyl terephthalate Usage And Synthesis
DescriptionThe mono-methyl terephthalate is a kind of phthalate ester. It can be obtained during the hydrolytical transformation process of dimethyl terephthalate (DMT) by some microbes such as Rhodococcus rubber and Pasteurella multocida. It is also the intermediate during the manufacturing of dimethyl terephthalate, terephthalic acid and some other derivatives. As the ester form of terephthalate, it is widely used for the manufacturing of plastics, paints, synthetic fibers and polyester.
ReferencesSchoengen, Anton, Georg Schreiber, and Heinz Schroeder. U.S. Patent No. 4,302,595. 24 Nov. 1981.
Li, Jiaxi, Ji-Dong Gu, and Li Pan. International Biodeterioration & Biodegradation 55.3 (2005): 223-232.
Li, Jiaxi, Ji-Dong Gu, and Jun-hua Yao. International Biodeterioration & Biodegradation 56.3 (2005): 158-165.

Chemical Propertieswhite to off-white powder
Usesmono-Methyl Terephthalate is used in the synthesis of Hepatits C antiviral activity. Also used in the design and preparation of benzamide derivatives as BRAFV600E inhibitors, which if mutated, can influence malignancies and melanomas.
Dioctyl terephthalate 1,4,5,8-Naphthalenetetracarboxylic dianhydride Dacthal Methyl Bensulfuron methyl CHLORTHAL MONOMETHYL ESTER BIS(HEXAFLUOROISOPROPYL)TEREPHTHALATE TETRAMETHYL PYROMELLITATE 6-CARBOXYFLUORESCEIN DIACETATE ACETYL-COA: ORTHOPHOSPHATE ACETYLTRANSFERASE Kresoxim-methyl mono-Methyl terephthalate Thiophanate-methyl 6-Carboxyfluorescein DIETHYL TEREPHTHALATE DIPHENYL TEREPHTHALATE METSULFURON METHYL Dimethyl nitroterephthalate
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