4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt

4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt Basic information
Product Name:4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt
Synonyms:P-CHLOROMERCURIPHENYLSULFONIC ACID;PCMBS;4-(chloromercuri)benzenesulfonic acid monosodium salt;P-chloromercuriphenylsulfonic acid*monosodium;sodium 4-(chloromercurio)benzenesulphonate;4-(Chloromercuri)benzenesulfonic ,sodium salt;4-(CHLOROMERCURI)BENZENESULFONIC ACID, SODIUM SALT;p-Chloromercuriphenylsulfonic Acid, PCMBS
CAS:14110-97-5
MF:C6H4ClHgNaO3S
MW:415.19
EINECS:
Product Categories:MTS and Sulfhydryl Active Reagents;MTS & Sulfhydryl Active Reagents;Aromatics
Mol File:14110-97-5.mol
4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt Structure
4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt Chemical Properties
Melting point >370°C
storage temp. Amber Vial, -20°C Freezer
solubility DMSO (Slightly, Heated), Water (Slightly)
form Solid
color Off-White to Light Grey
Stability:Store at -20°C
Safety Information
Hazard Codes T
RIDADR 2025
Hazard Note Toxic
HazardClass 6.1(a)
PackingGroup II
MSDS Information
4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt Usage And Synthesis
Chemical PropertiesOff-White Powder
UsesA useful sulfhydryl reagent, 4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt reacts with Histidine 225C, a residue of the NhaA-Na/H Antiporter of Escherichia Coli. More soluble than p-chloromercuribenzoic acid
Purification MethodsThe free acid is obtained by acidifying an aqueous solution, filtering off the acid, washing it with H2O and recrystallising from hot H2O to give a colourless solid which is dried in a vacuum over P2O5 and should be free of Cl-ions (AgNO3 test). The Na salt is made by dissolving it in one equivalent of aqueous NaOH and evaporating to dryness. [Nesmejanow et al. Chem Ber 67 130 1934, Boyer J Am Chem Soc 76 4331 1954.] HIGHLY TOXIC.
4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt Preparation Products And Raw materials
METHYLMERCURY(II) CHLORIDE Benzenesulfonic acid 4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt Mercury PHENYLMERCURIC CHLORIDE SODIUM MERCURY AMALGAM

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