tert-Butyl Hypochlorite

tert-Butyl Hypochlorite Basic information
Product Name:tert-Butyl Hypochlorite
Synonyms:HYPOCHLOROUS ACID TERT-BUTYL ESTER;Hypochlorous acid, 1,1-dimethylethyl ester;Hypochlorousacid,1,1-dimethylethylester;t-Butyl hypochlorite;tert-C4H9OCl;2-chlorosyl-2-methylpropane;2-chlorosyl-2-methyl-propane;1,1-Dimethylethyl hypochlorite
CAS:507-40-4
MF:C4H9ClO
MW:108.57
EINECS:208-072-7
Product Categories:Miscellaneous Reagents;Chlorination;Halogenation;Oxidation;Synthetic Organic Chemistry
Mol File:507-40-4.mol
tert-Butyl Hypochlorite Structure
tert-Butyl Hypochlorite Chemical Properties
Boiling point 79.6℃ (750 Torr)
density 0.96
refractive index 1.4010-1.4050
storage temp. Refrigerator
solubility Chloroform (Sparingly), Ethyl Acetate (Slightly)
form Oil
color Pale Yellow to Yellow
Merck 14,1571
Stability:Unstable. Light-sensitive. Highly flammable. Incompatible with strong oxidizing agents. Keep refrigerated below 10 C.
InChIKeyIXZDIALLLMRYOU-UHFFFAOYSA-N
EPA Substance Registry SystemHypochlorous acid, 1,1-dimethylethyl ester (507-40-4)
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
RIDADR 3255
HazardClass 4.2/8
HS Code 29209090
MSDS Information
tert-Butyl Hypochlorite Usage And Synthesis
Chemical Propertiesyellowish liquid with an irritating odour
UsesDehydration of alcohols; N- and C-chlorinations.
UsesHypochlorous Acid tert-Butyl Ester_x000D__x000D_DISCONTINUED (cas# 507-40-4) is a compound useful in organic synthesis.
General DescriptionA slightly yellowish liquid with a pungent odor. Water insoluble. Flash point near 0°F. Corrosive to the skin, eyes, and mucous membranes.
Air & Water ReactionsMay ignite on contact with air or moist air. May burn rapidly with flare-burning effect. Water insoluble. Decomposed exothermically by water with the evolution of toxic chlorine gas.
Reactivity ProfileHYPOCHLOROUS ACID TERT-BUTYL ESTER decomposes exothermically when exposed to UV light to give acetone and chloromethane. Glass containers have burst because of pressure buildup after exposure to fluorescent lighting or daylight. Reacts violently with rubber. Should not be heated to its boiling point.
Health HazardFire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
Fire HazardFlammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.
tert-Butyl Hypochlorite Preparation Products And Raw materials
Preparation Products4,5-Difluoroindoline-2,3-dione-->N-CHLOROACETANILIDE-->5-CHLOROVANILLIN-->chlorocyclopropane
Iron(III) trifluoromethanesulfonate 4-Bromophenoxybenzene 5-Bromo-3-nitropyridine-2-carbonitrile Oxyclozanide DL-Mandelic acid 5-CYANO-2-FLUOROBENZALDEHYDE 1-Iodoheptane 4-BROMO-3-NITROANILINE White oil ETHYL 2-METHYLTHIAZOLE-4-CARBOXYLATE Menthyl acetate 2-Fluoro-4-methylpyridine 1-Ethylcyclopentanol (2-FLUORO-BENZYL)-HYDRAZINE N-TERT-BUTYLBENZENESULFENAMIDE Methyl 2-chloro-4-fluorobenzoate Iodine pentafluoride tert-Butyl Hypochlorite

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