1-METHYL-4-(METHYLSULFINYL)BENZENE

1-METHYL-4-(METHYLSULFINYL)BENZENE Basic information
Product Name:1-METHYL-4-(METHYLSULFINYL)BENZENE
Synonyms:Methyl p-methylphenylsulfoxide;METHYL P-TOLYL SULFOXIDE;1-METHYL-4-(METHYLSULFINYL)BENZENE;1-(Methylsulfinyl)-4-methylbenzene;4-(Methylsulfinyl)toluene;4-Methylphenyl (methyl) sulfoxide;Methyl 4-methylphenyl sulphoxide;1-Methyl-4-(methylsulphinyl)benzene, Methyl p-tolyl sulphoxide
CAS:934-72-5
MF:C8H10OS
MW:154.23
EINECS:
Product Categories:Organic Building Blocks;Sulfoxides;Sulfur Compounds;Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfur Compounds
Mol File:934-72-5.mol
1-METHYL-4-(METHYLSULFINYL)BENZENE Structure
1-METHYL-4-(METHYLSULFINYL)BENZENE Chemical Properties
Melting point 44-46 °C (lit.)
Boiling point 113-114 °C/2 mmHg (lit.)
density 1.1125 (rough estimate)
refractive index 1.5780 (estimate)
Fp >230 °F
solubility soluble in Methanol
form powder to crystal
color White to Almost white
Safety Information
WGK Germany 3
HS Code 29309099
MSDS Information
ProviderLanguage
SigmaAldrich English
1-METHYL-4-(METHYLSULFINYL)BENZENE Usage And Synthesis
UsesMethyl p-tolyl sulfoxide may be used as a catalyst in the preparation of homoallylic alcohols by the allylation of aldehydes with allyltrichlorosilane. It may be used as a ligand in the synthesis of molybdenum chlorocomplexes.
Synthesis Reference(s)Chemistry Letters, 15, p. 967, 1986
Synthetic Communications, 19, p. 1569, 1989 DOI: 10.1080/00397918908051052
Tetrahedron Letters, 19, p. 3415, 1978
General DescriptionMethyl p-tolyl sulfoxide (MTSO), an alkyl-substituted p-tolyl sulfoxide, is a Lewis base. It behaves as an activator of silicon tetrachloride that is employed in aza-Diels-Alder reaction.
1-METHYL-4-(METHYLSULFINYL)BENZENE Preparation Products And Raw materials
DIMETHYL DIPHENYL SULFONE 4,4'-DICARBOXYLATE 4'-METHYL-2(P-TOLYL SULFONYL)ACETOPHENONE PHENYL P-TOLYL SULFONE 4-TOLUENESULFONYLACETIC ACID 2-(P-TOLUENESULFONYL)ACETOPHENONE 4-METHANESULFONYL-3-NITRO-BENZOIC ACID METHYL P-TOLUENESULPHONYLACETATE Tosylmethyl isocyanide 4-Methylsulphonylacetophenone 1-Methyl-4-(methylsulfonyl)-benzene 4,4'-Dimethyldiphenylsulfoxide 2-(ethylsulfonyl)-5-(trifluoromethyl)aniline N,N-BIS(P-TOLYLSULFONYLMETHYL)ETHYLAMINE N-AMINO-2-((4-METHYLPHENYL)SULFONYL)ETHANAMIDE METHYLTHIOMETHYL P-TOLYL SULFONE 4,4'-SULFONYLBIS-BENZOIC ACID Tosyl cyanide 2-((4-METHYLPHENYL)SULFONYL)ETHANAMIDE

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