ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Hydrocarbon halides 4-Chlorobenzyl bromide

4-Chlorobenzyl bromide

4-Chlorobenzyl bromide Basic information
Product Name:4-Chlorobenzyl bromide
Synonyms:1-(Bromomethyl)-4-chlorobenzene;ALPHA-BROMO-4-CHLOROTOLUENE;4-CHLOROBENZYL BROMIDE;4CBB;à-bromo-4-chlorotoluene;4-Chlorobenzyl bromide 98%;4-Chlorobenzyl bromide, 98+%;4-Chlorophenylmethyl bromide
CAS:622-95-7
MF:C7H6BrCl
MW:205.48
EINECS:210-760-7
Product Categories:Benzyl;Aryl;C7;Halogenated Hydrocarbons
Mol File:622-95-7.mol
4-Chlorobenzyl bromide Structure
4-Chlorobenzyl bromide Chemical Properties
Melting point 48-52 °C (lit.)
Boiling point 107-108°C 8mm
density 1.570±0.06 g/cm3(Predicted)
Fp >230 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform, Dichloromethane (Slightly)
form Crystalline Low Melting Solid
color White
Water Solubility Insoluble in water.
Sensitive Lachrymatory
BRN 606497
InChIKeyKQNBRMUBPRGXSL-UHFFFAOYSA-N
CAS DataBase Reference622-95-7(CAS DataBase Reference)
NIST Chemistry Reference4-Chlorobenzyl bromide(622-95-7)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 1759 8/PG 2
WGK Germany 3
Hazard Note Corrosive/Lachrymatory
HazardClass 6.1
PackingGroup II
HS Code 29049090
MSDS Information
ProviderLanguage
1-(Bromomethyl)-4-chlorobenzene English
SigmaAldrich English
ALFA English
4-Chlorobenzyl bromide Usage And Synthesis
Chemical PropertiesWhite crystalline low melting solid
Uses4-Chlorobenzyl bromide is used as pharmaceutical intermediate.
Uses4-Chlorobenzyl bromide may be used to synthesize 1-(4-chlorobenzyl)-2-(pyrrolidin-1-yl-methyl)-1H-benzimidazole dihydrochloride
General Description4-Chlorobenzyl bromide undergoes carbonylation in the presence of dimer of chloro(1,5-cyclooctadiene)rhodium(I) to yield the corresponding phenylacetic acid. It can be synthesized by reacting 4-chlorobenzyl alcohol with bromodimethylsulfonium bromide (BDMS) It can also be synthesized by refluxing a mixture of 4-chlorobenzaldehyde, chlorotrimethylsilane, 1,1,3,3-tetramethyldisiloxane and lithium bromide.
4-Chlorobenzyl bromide Preparation Products And Raw materials
Preparation Products3-CHLOROBENZAL BROMIDE-->NSC 62608-->BenzeneMethanaMine, 4-chloro-N,N-diMethyl--->1-(4-chloro-phenyl)-4,4-dimethyl-2-[1,2,4]triazol-1-yl-pentan-3-one-->DL-4-Chlorophenylalanine-->TRIMETHYLGERMANIUM BROMIDE-->(-)-4-Chlorobenzhydrylamine-->Chlormidazole-->CHLORBENSIDE-SULFONE-->1-(4-CHLOROBENZYL)PIPERAZINE-->(4-CHLORO-BENZYL)-METHYL-AMINE-->Isopropyl(4-chlorophenyl)acetyl chloride-->1-[(4-chlorophenyl)methyl]-3-nitro-1H-pyrazole-->1-(4-chlorobenzyl)-4-methylpiperazine
2,3-DIBROMO-3-(4-CHLOROPHENYL)PROPANOIC ACID 2,3-DIBROMO-3-(3,4-DICHLOROPHENYL)-1-(2-NITROPHENYL)PROPAN-1-ONE 2,4-DICHLORO-5-FLUOROBENZYL BROMIDE 4-Methoxybenzylchloride 4-Chlorobenzyl cyanide 3-Chlorobenzyl chloride BRETYLIUM TOSYLATE 3-BROMO-3-[BROMO(4-CHLOROPHENYL)METHYL]CHROMAN-4-ONE 2-Fluoro-4-chlorobenzyl bromide 4-Chlorobenzyl bromide Benzyl bromide 4-Fluorobenzyl chloride Ethidium bromide 1,2-Dichloro-4-(chloromethyl)benzene Allyl bromide Benzyl chloroformate 4-Chlorobenzyl chloride Methyl bromide
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