3-Methacryloxypropyltrimethoxysilane

3-Methacryloxypropyltrimethoxysilane Basic information
Introduction
Product Name:3-Methacryloxypropyltrimethoxysilane
Synonyms:METHACRYLIC ACID 3-(TRIMETHOXYSILYL)PROPYL ESTER;BIND-SILANE;UNION CARBIDE SILANE ADHESION PROMOTER A-174;(3-hydroxypropyl)trimethoxy-silanmethacrylate;(gamma-(methacryloyloxy)propyl)trimethoxysilane;[gamma-(Methacryloyloxy)propyl]trimethoxysilane;1-Propanol, 3-(trimethoxysilyl)-, methacrylate;2-methyl-2-propenoicaci3-(trimethoxysilyl)propylester
CAS:2530-85-0
MF:C10H20O5Si
MW:248.35
EINECS:219-785-8
Product Categories:Isoquinolines ,Quinolines ,Quinazolines ,Quinaldines;Adhesion Promoters;Coupling Agents;Dispersing Agents;Methacrylate Silanes;Surface Modifiers;Acrylate;monomer;silane;Industrial/Fine Chemicals;Chloroalkylsilanes, etc. (Silane Coupling Agents);Functional Materials;Si (Classes of Silicon Compounds);Silane Coupling Agents;Si-O Compounds;Trialkoxysilanes;Vinylsilanes, Allylsilanes;Ion Sensor Materials;Plasticizer for ISE;Self-Assembly Materials;Analytical/Chromatography;Chemical Synthesis;Contact Printing;Materials Science;Micro/NanoElectronics;Organometallic Reagents;Organosilicon;Self Assembly &;Silanes;Acrylic Monomers;Methacrylate;Monomers;Polymer Science;2530-85-0
Mol File:2530-85-0.mol
3-Methacryloxypropyltrimethoxysilane Structure
3-Methacryloxypropyltrimethoxysilane Chemical Properties
Melting point <-50°C
Boiling point 190 °C(lit.)
density 1.045 g/mL at 25 °C(lit.)
vapor pressure 0-12790Pa at 20-25℃
refractive index n20/D 1.431(lit.)
Fp 198 °F
storage temp. 2-8°C
form Liquid
Specific Gravity1.045
color Clear
Water Solubility Miscible with water.
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 1952435
InChIKeyXDLMVUHYZWKMMD-UHFFFAOYSA-N
LogP-0.9-2.1 at 20-21℃
CAS DataBase Reference2530-85-0(CAS DataBase Reference)
NIST Chemistry Reference3-(Methacryloxy)propyltrimethoxysilane(2530-85-0)
EPA Substance Registry System3-(Trimethoxysilyl)propyl methacrylate (2530-85-0)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-37/38-22
Safety Statements 26-28-37/39
RIDADR 3082
WGK Germany 1
RTECS UC0230000
4.4-8-21
TSCA Yes
HS Code 29161290
Hazardous Substances Data2530-85-0(Hazardous Substances Data)
ToxicityLD50 oral in rat: 22600uL/kg
MSDS Information
ProviderLanguage
Silane A-174 English
SigmaAldrich English
ACROS English
ALFA English
3-Methacryloxypropyltrimethoxysilane Usage And Synthesis
Introduction3-Methacryloxypropyltrimethoxysilane is a methacryl-functional silane, it is a clear, light and heat sensitive liquid with a faintly sweet odour.
3-Methacryloxypropyltrimethoxysilane is used as adhesion promoter at organic/inorgainc interfaces, as surface modifier (e.g. imparting water repellency, organophilic surface adjustment) or as crosslinking of polymers). It is used as a coupling agent to improve the physical and electrical properties of glass-reinforced and mineral-filled thermosetting resins under exposure to heat and/or moisture. It is typically employed as a blend additive in resin systems that cure via a free radical mechanism (e.g. polyester, acrylic) and in filled or reinforced thermoplastic polymers, including polyolefins and polyurethanes. It is also used to functionalize resins via radical initiated processes - copolymerization or grafting - and to modify surfaces.
Applications:
  • 3-Methacryloxypropyltrimethoxysilane can improve strength as glass fiber size composite in reinforced polyester composites.
  • Enhance initial and wet strength of reinforced polyester resin composites.
  • Enhance the wet electrical properties of many mineral-filled and reinforced composites.
  • Crosslinked acrylic type resins can improve adhesion and durability of adhesives and coatings.


Chemical PropertiesColorless transparent liquid
Uses3-(Methacryloyloxy)propyltrimethoxysilane (MPS) acts as a functional comonomer, which is used to prepare polystyrene latex having silanol by emulsion polymerization. It is used in the preparation of polymers in association with other monomers like vinyl acetate, acrylic acid and methyl acrylic acid used in coating, adhesive and sealing agents, which provides excellent adhesion and durability. The composite materials made from unsaturated polyester by using MPS improve mechanical property.
General Description3-(Trimethoxysilyl)propyl methacrylate (TMSPMA) is a hydrophobic monomer. The presence of an additional functional group of acrylate facilitates TMSPMA for grafting polymerization on plastic surfaces. 3-(Trimethoxysilyl)propyl methacrylate undergoes first-order kinetic polymerization to form polyTMSPMA, which is a moisture stable polymer.
Flammability and ExplosibilityNotclassified
3-Methacryloxypropyltrimethoxysilane Preparation Products And Raw materials
Raw materialsMethanol-->Methyl methacrylate-->Trichlorosilane
Silane coupler KH-602 N-(3-Triethoxysilylpropyl)ethylenediamine 3-(2-Aminoethylamino)propyl-dimethoxymethylsilane 3-Chloropropylmethyldimethoxysilane 3-Mercaptopropyltriethoxysilane 3-METHACRYLOXYPROPYLTRIS(METHOXYETHOXY)SILANE Trimethoxypropylsilane Propyl gallate 3-(TRIMETHOXYSILYL-D9)PROPYL METHACRYLATE Silicon tetrahydride METHACRYLOXYPROPYLSILATRANE Trimethoxysilylpropanethiol SILANE COUPLING AGENT CALCIUM ACRYLATE 3-(Triethoxysilyl)propyl methacrylate METHACRYLOXYPROPYLTRIISOPROPOXYSILANE N-PROPYL METHACRYLATE Propyl butyrate Trimethoxysilylpropyl Methacrylate

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