Monoacetin

Monoacetin Basic information
Product Name:Monoacetin
Synonyms:1,2,3-propanetriol1-acetate;1-Monoacetin;2,3-Dihydroxypropyl acetate;Acetic acid, monoglyceraldehyde;Acetin, mono-;Acetoglyceride;Acetyl monoglyceride;acetylmonoglyceride
CAS:26446-35-5
MF:C5H10O4
MW:134.13
EINECS:247-704-6
Product Categories:
Mol File:26446-35-5.mol
Monoacetin Structure
Monoacetin Chemical Properties
Melting point 3 °C
Boiling point 258 °C
density 1.21
Fp 145 °C
refractive index 1.4500
Specific Gravity1.2060 (20℃)
Water Solubility soluble
Sensitive Hygroscopic
Merck 14,6242
Exposure limitsOSHA: TWA 15 mg/m3; TWA 5 mg/m3
LogP-1.215 (est)
CAS DataBase Reference26446-35-5(CAS DataBase Reference)
NIST Chemistry ReferenceMonoacetine(26446-35-5)
EPA Substance Registry SystemGlyceryl monoacetate (26446-35-5)
Safety Information
Risk Statements 68
Safety Statements 24/25
RTECS AK3595000
TSCA Yes
Hazardous Substances Data26446-35-5(Hazardous Substances Data)
MSDS Information
ProviderLanguage
1,2,3-Propanetriol monoacetate English
ACROS English
ALFA English
Monoacetin Usage And Synthesis
Chemical PropertiesClear colorless to pale yellow viscous liquid
UsesIn manufacture of smokeless powder and dynamite; as a solvent for basic dyes; in tanning leather.
UsesGlycerol monoacetate is used for production of tanning leather and dye. It is also used as a solvent.
Production MethodsMonoacetin is manufactured by heating glycerol with acetic acid.
Synthesis Reference(s)Journal of the American Chemical Society, 82, p. 4883, 1960 DOI: 10.1021/ja01503a033
General DescriptionClear colorless to pale yellow viscous liquid with a characteristic odor.
Air & Water ReactionsVery hygroscopic. Soluble in water.
Reactivity ProfileMonoacetin may hydrolyze in acid or alkaline aqueous solutions. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. They exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Fire HazardMonoacetin is probably combustible.
Monoacetin Preparation Products And Raw materials
Preparation ProductsGlycidol
Sodium acetate Glyceryl Monooleate Span 60 POLYGLYCERYL-10 OLEATE Span 20 Monostearin beta-D-Ribofuranose 1,2,3,5-tetraacetate Dibenzoyltartaric acid Cellulose acetate Glycerol Monoacetin Triglycerol monostearate ACETATE Diacetin, mixed isomers, tech. ca 50%, remainder triacetin + monoacetin Vinyl acetate Benzyl acetate Ammonium acetate PHOSPHOGLYCOLIC ACID

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