1,4-Bis(diphenylphosphino)butane-palladium(II) chloride

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Basic information
Reaction
Product Name:1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
Synonyms:Palladium(ii) chloride 1,4-b;1,4-Bis(diphenylphosphino)butane-palladium(II) chloride,98+%;Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II), Palladium(II) chloride 1,4-bis(diphenylphosphino)butane complex;Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6%;1,4-Butylenebis(diphenylphosphine)-palladium dichloride;Dichloro[1,4-bis(diphenylphosphino)butane]palladium (II) ,98%;4-Bis(diphenylphosphino)butane-palladiuM(II) chloride;PDCI2(DPPB)
CAS:29964-62-3
MF:C28H28P2.Cl2Pd
MW:603.8
EINECS:678-067-6
Product Categories:Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Metal Compounds;Pd
Mol File:29964-62-3.mol
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Structure
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Chemical Properties
Melting point 285-305 °C
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Soluble in ethanol, benzene, and ethereal solvents.
form Powder
color light-yellow
InChIKeyJQXJBXVWVPVTOO-UHFFFAOYSA-L
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38
Safety Statements 24/25-36-27
WGK Germany 3
1-10
HS Code 28439000
MSDS Information
ProviderLanguage
SigmaAldrich English
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Usage And Synthesis
Reaction
  1. Catalyst for the Grignard coupling for regioand stereoselective monoalkylation and arylation of 1,1-dichloro-1-alkenes
  2. Synthetic pyrethriods: catalyst for the Negishi coupling of (2,2-dihaloethenyl)cyclopropanecarboxylates
Reactions of 29964-62-3
Chemical Propertiesyellow solid
UsesDichloro[bis(1,4-diphenylphosphino)butane]palladium(II) is used for the catalysis of styrene carbonylation, coupling of alkyl Grignard reagents with organic halides, selective monoalkylation of organic polyhalides, and modification of the dihalovinyl moiety of synthetic pyrethroids.
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Preparation Products And Raw materials
Raw materialsBis(benzonitrile)palladium chloride-->1,4-Bis(diphenylphosphino)butane
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Phenyl phosphine Methylene Chloride Diphenylphosphine 1,4-Bis(diphenylphosphino)butane DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE Sodium chloride Palladium 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Chlorodiphenylphosphine N-(Carboxymethyl)-N-(phosphonomethyl)-glycine CIS-DICHLOROBIS(DIMETHYLPHENYLPHOSPHINE)PALLADIUM(II) Palladium chloride N-BUTANE tert-Butylchlorodiphenylsilane 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile

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