2,2'-DINITROBIPHENYL

2,2'-DINITROBIPHENYL Basic information
Product Name:2,2'-DINITROBIPHENYL
Synonyms:2,2'-Dinitro-1,1'-biphenyl;2,2'-Dinitrobiphenyl, 2,2'-dinitro-;Biphenyl, 2,2'-dinitro-;RARECHEM AQ BD 0003;1-nitro-2-(2-nitrophenyl)benzene;6,6-dinitro-1-phenylcyclohexa-1,3-diene;2,2'-DINITROBIPHENYL;2,2-DINITROBIPHENYL
CAS:2436-96-6
MF:C12H8N2O4
MW:244.2
EINECS:219-435-4
Product Categories:Aromatic Hydrocarbons (substituted) & Derivatives;Building Blocks;Chemical Synthesis;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks;Biphenyls (for High-Performance Polymer Research);Functional Materials;Reagent for High-Performance Polymer Research;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks
Mol File:2436-96-6.mol
2,2'-DINITROBIPHENYL Structure
2,2'-DINITROBIPHENYL Chemical Properties
Melting point 124-126 °C(lit.)
Boiling point 305°C
density 1,45 g/cm3
refractive index 1.6360 (estimate)
Fp 305°C
storage temp. Sealed in dry,2-8°C
form powder to crystal
color White to Light yellow
Water Solubility Insoluble in water
BRN 1579851
CAS DataBase Reference2436-96-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29042090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
2,2'-DINITROBIPHENYL Usage And Synthesis
Chemical Propertieslight yellow to beige crystalline powder
Uses2,2?-Dinitrobiphenyl has been used as an internal standard in the determination of p,p?-DDT in technical and formulated products using gas chromatographic method
Uses2,2′-Dinitrobiphenyl has been used as an internal standard in the determination of p,p′-DDT in technical and formulated products using gas chromatographic method.
DefinitionChEBI: Biphenyl substituted with nitro groups at the 2- and 2'-positions.
Synthesis Reference(s)Organic Syntheses, Coll. Vol. 3, p. 339, 1955
The Journal of Organic Chemistry, 53, p. 4482, 1988 DOI: 10.1021/jo00254a012
Tetrahedron Letters, 16, p. 143, 1975
General DescriptionThe electroreduction of 2,2′-dinitrobiphenyl in anionic, cationic, and nonionic micellar solutions has been studied by polarography and cyclic voltammetry.
Purification MethodsCrystallise the biphenyl from EtOH, AcOH (m 124.5o) or pet ether (m 125.5-126o). [Beilstein 5 H 538, 5 III 1759, 5 IV 1826.]
2,2'-DINITROBIPHENYL Preparation Products And Raw materials
Raw materials2-Nitrobenzoic acid
2,4,5,7-TETRANITRO-9H-FLUORENE 2-(2,4,5,7-TETRANITRO-9H-FLUOREN-9-YLIDEN)MALONONITRILE 4,5,7-TRINITRO-9-OXO-9H-FLUORENE-2-CARBOXYLIC ACID 2,4,5,7-TETRANITRO-9-FLUORENONE 4,5-DINITRO-9H-FLUORENE-2,7-DISULFONYL DICHLORIDE,97% N,N-DIMETHYL-N-[(2,4,5,7-TETRANITRO-9H-FLUOREN-9-YLIDEN)METHYL]AMINE (+)-ALPHA-(2,4,5,7-TETRANITRO-9-FLUORENYLIDENEAMINOXY)PROPIONIC ACID 9-[4-(HEXYLOXY)BENZYLIDENE]-2,4,5,7-TETRANITRO-9H-FLUORENE 2-[2-(DIMETHYLAMINO)-4,5,7-TRINITRO-9H-FLUOREN-9-YLIDEN]MALONONITRILE 4,5-DINITRO-9-OXO-9H-FLUORENE-2,7-DISULFONYL DICHLORIDE,97% 2,2'-DINITROBIPHENYL 2-(DIMETHYLAMINO)-4,5,7-TRINITRO-9H-FLUOREN-9-ONE 9-BENZYLIDENE-2,4,5,7-TETRANITRO-9H-FLUORENE (-)-ALPHA-(2,4,5,7-TETRANITRO-9-FLUORENYLIDENEAMINOXY)PROPIONIC ACID 2,4,5,7-TETRANITRO-9-(4-PROPOXYBENZYLIDENE)-9H-FLUORENE 6,6'-Dinitrodiphenic acid (+),(-)-A-2,4,5,7-TETRANITRO-9-FLUORENYLIDENEAMINOOXYPROPIONIC ACID 9-(4-METHOXYBENZYLIDENE)-2,4,5,7-TETRANITRO-9H-FLUORENE

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