1,3,5-Triaza-7-phosphaadamantane,min.97%

1,3,5-Triaza-7-phosphaadamantane,min.97% Basic information
Reaction
Product Name:1,3,5-Triaza-7-phosphaadamantane,min.97%
Synonyms:1,3,5-Triaza-7-phosphaadamantane,min.97%;1,3,5-TRIAZA-7-PHOSPHAADAMANTANE, MIN. 97%;1,3,5-Triaza-7-phosphaadamantane;1,3,5-Triaza-7-phosphatricyclo[3.3.1.13.7]decane, NSC 266642, PTA;1,3,5-Triaza-7-phosphatricyclo[3.3.1.13,7]decane;1,3,5-Triaza-9-phospha-adamantane;Nsc266642;1,3,5-Triaza-7-phosphaadaMantane, Min. 97% PTA
CAS:53597-69-6
MF:C6H12N3P
MW:157.15
EINECS:
Product Categories:organophosphine ligand
Mol File:53597-69-6.mol
1,3,5-Triaza-7-phosphaadamantane,min.97% Structure
1,3,5-Triaza-7-phosphaadamantane,min.97% Chemical Properties
Melting point 244-250 °C
Boiling point 232.5±40.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka5.78±0.20(Predicted)
form Solid
color White
Sensitive Hygroscopic
Safety Information
WGK Germany 3
HS Code 2934999090
MSDS Information
1,3,5-Triaza-7-phosphaadamantane,min.97% Usage And Synthesis
Reaction
  1. Air-stable, water-soluble version of trimethylphosphine.
  2. Reagent used in the β-olefination of 2-alkynoates leading to trisubstituted 1,3-dienes.
  3. Ligand/rhodium catalyst used in the branch selective allylation of acetylacetone.
  4. Ligand/oxorhenium complex used as a catalyst for the Baeyer-Villiger oxidation of ketones. 
Reactions of 53597-69-6
General DescriptionAir stable organocatalyst for Baylis-Hillman transformation
1,3,5-Triaza-7-phosphaadamantane,min.97% Preparation Products And Raw materials
Preparation ProductsDAPTA-->1,3,5-Triaza-7-phosphatricyclo[3.3.1.13,7]decane, 7-oxide
Aluminum dihydrogen phosphate Phosphorus pentoxide 1,3,5-Triaza-7-phosphaadamantane,min.97%

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