ChemicalBook Product Catalog Organic Chemistry Phosphines tert-Butyl diethylphosphonoacetate

tert-Butyl diethylphosphonoacetate

tert-Butyl diethylphosphonoacetate Basic information
Product Name:tert-Butyl diethylphosphonoacetate
Synonyms:DIETHYL(2-TERT-BUTOXYCARBONYLMETHYL)PHOSPHONATE;(DIETHOXYPHOSPHORYL)ACETIC ACID TERT-BUTYL ESTER;DIETHYL (BOC-METHYL)PHOSPHONATE;DIETHYLPHOSPHONOACETIC ACID TERT-BUTYL ESTER;DIETHYL (TERT-BUTOXYCARBONYLMETHYL)PHOSPHONATE;T-BUTYL DIETHYL PHOSPHONOACETATE;TERT-BUTYL DIETHYLPHOSPHONOACETATE;tert-Butyl diethylphosphonoacetate, 98 %
CAS:27784-76-5
MF:C10H21O5P
MW:252.24
EINECS:000-000-0
Product Categories:C-C Bond Formation;Horner-Wadsworth-Emmons Reagents;Olefination;27784-76-5
Mol File:27784-76-5.mol
tert-Butyl diethylphosphonoacetate Structure
tert-Butyl diethylphosphonoacetate Chemical Properties
Boiling point 100-103 °C/1.5 mmHg (lit.)
density 1.074 g/mL at 25 °C (lit.)
refractive index n20/D 1.431(lit.)
Fp >230 °F
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Liquid
Specific Gravity1.074
color Clear colorless
Water Solubility Not miscible or difficult to mix in water.
BRN 2050126
CAS DataBase Reference27784-76-5(CAS DataBase Reference)
Safety Information
Risk Statements 36/38
Safety Statements 26-36-24/25
WGK Germany 3
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
tert-Butyl diethylphosphonoacetate Usage And Synthesis
Chemical PropertiesClear colorless liquid
Usestert-Butyl diethylphosphonoacetate is used as a reactant for preparation of hydroxymethylated dihydroxyvitamin D3 analogs via Wittig-Horner approach, as potential antitumor agents, synthesis of phosphopeptide mimetic prodrugs targeted to Src homology 2 (SH2) domain of signal transducer and activator of transcription 3 (Stat 3) and bicyclic triaminophosphine-promoted stereoselective synthesis of a,?-unsaturated esters, fluorides, and nitriles from aldehydes and ketones using Wadsworth-Emmons phosphonates
tert-Butyl diethylphosphonoacetate Preparation Products And Raw materials
Preparation ProductsMethyl diethylphosphonoacetate-->(E)-tert-butyl 3-(4-cyanophenyl)acrylate-->TERT-BUTYL (3S)-3-AMINO-5-METHYLHEXANOATE, 97
TRIETHYL PHOSPHONOACETATE t-butyl chloroformate Cyhalofop-butyl DIMETHYLPHOSPHONOACETIC ACID Buprofezin tert-Butyl diethylphosphonoacetate Mefenpyr-diethyl Ethyl dimethylphosphonoacetate tert-Butyl chloroacetate tert-Butyl bromoacetate TERT-BUTYL ISOCYANIDE Diethyl malonate Diethyl carbonate tert-Butyl glycinate DI-TERT-BUTYL ETHER Methyl diethylphosphonoacetate tert-Butyl carbazate DIETHYLPHOSPHONOACETIC ACID
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