5-(4-DIMETHYLAMINOBENZYLIDENE)RHODANINE

5-(4-DIMETHYLAMINOBENZYLIDENE)RHODANINE Basic information
Product Name:5-(4-DIMETHYLAMINOBENZYLIDENE)RHODANINE
Synonyms:5-(4-Dimethylaminobenzylidene)rhodanine 98%;5-(4-Dimethylaminobenzylidene)rhodanine,99%;(5E)-5-[4-(dimethylamino)benzylidene]-2-mercapto-1,3-thiazol-4(5H)-one;4-Dimethylaminobenzalrhodanine 5-(4-Dimethylaminobenzylidene)-2-thioxo-4-thiazolidinone;5-[4-(Dimethylamino)benzylidene]-2-thioxo-4-thiazolidone;(E)-5-(4-(diMethylaMino)benzylidene)-2-thioxothiazolidin-4-one;Rose Red Silver reagents;5-((4-(dimethylamino)phenyl)methylene)-2-thioxo-4-thiazolidinon
CAS:536-17-4
MF:C12H12N2OS2
MW:264.37
EINECS:208-625-2
Product Categories:Building Blocks;Heterocyclic Building Blocks;Thiazoles
Mol File:536-17-4.mol
5-(4-DIMETHYLAMINOBENZYLIDENE)RHODANINE Structure
5-(4-DIMETHYLAMINOBENZYLIDENE)RHODANINE Chemical Properties
Melting point 285-288 °C(lit.)
density 1.36±0.1 g/cm3 (20 ºC 760 Torr)
refractive index 1.5950 (estimate)
storage temp. Store below +30°C.
solubility dioxane: soluble0.1g/10 mL (hot)
form Fluffy Powder
pka8.17±0.30(Predicted)
color Red
Water Solubility Insoluble in water, 993.7(mg/L) at 25°C
Merck 14,3231
BRN 189065
CAS DataBase Reference536-17-4(CAS DataBase Reference)
EPA Substance Registry System4-Thiazolidinone, 5-[[4-(dimethylamino)phenyl]methylene]-2-thioxo- (536-17-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 22-24/25-36/37-26
WGK Germany 3
RTECS VI8090000
TSCA Yes
HazardClass IRRITANT
HS Code 29349990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
5-(4-DIMETHYLAMINOBENZYLIDENE)RHODANINE Usage And Synthesis
Chemical Propertiesred fluffy powder
Uses5-(4-Dimethylaminobenzylidene)rhodanine is a silver-specific dye that is used to quantitate the autoradiographic deposition of silver onto X-ray film in a colorimetric assay. 5-(4-Dimethylaminobenzylidene)rhodanine is used as an indicator in the titration of cyanide solution with silver nitrate solution.
UsesApplied for the detection of Ag, Au, Cu, Hg, Pd, Pt, alkaloids, antipyrin, indican, sulfonamide, urobilinogen. Reagent for the determination of silver, palladium, mercury and gold. Also used in the photometric determination of auto radiograms.
UsesAs 0.03% solution in acetone for detection of silver, mercury, copper, gold, platinum and palladium ions.
Safety ProfilePoison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of NOx and SOx
5-(4-DIMETHYLAMINOBENZYLIDENE)RHODANINE Preparation Products And Raw materials
(5E)-3-BENZYL-5-[4-(DIMETHYLAMINO)BENZYLIDENE]-2-THIOXO-1,3-THIAZOLIDIN-4-ONE AURORA 1057 AURORA 5861 (E)-5-(4-(DIETHYLAMINO)BENZYLIDENE)-3-(MORPHOLINOMETHYL)-2-THIOXOTHIAZOLIDIN-4-ONE AURORA 5541 AURORA 391 AURORA 9905 5-((4-(DIMETHYLAMINO)PHENYL)METHYLENE)-3-ETHYL-2-THIOXO-1,3-THIAZOLIDIN-4-ONE AKOS B018348 AURORA 7396 3-((5E)-5-[4-(DIMETHYLAMINO)BENZYLIDENE]-4-OXO-2-THIOXO-1,3-THIAZOLIDIN-3-YL)PROPANOIC ACID AURORA 3389 AURORA 1164 AURORA 5990 (5E)-5-[4-(DIMETHYLAMINO)BENZYLIDENE]-3-(4-METHOXYPHENYL)-2-THIOXO-1,3-THIAZOLIDIN-4-ONE AURORA 7114 ((5E)-5-[4-(DIMETHYLAMINO)BENZYLIDENE]-4-OXO-2-THIOXO-1,3-THIAZOLIDIN-3-YL)ACETIC ACID AURORA 7113

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