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| | ETHYL 3-BUTENOATE Basic information |
| Product Name: | ETHYL 3-BUTENOATE | | Synonyms: | 3-Butenoic acid ethyl ester;but-3-enoic acid ethyl ester;ethyl but-3-enoate;Vinylacetic acid ethyl ester;ETHYL 3-BUTENOATE;2-methyl-3-pentenoate;Monostearin Impurity 8 | | CAS: | 1617-18-1 | | MF: | C6H10O2 | | MW: | 114.14 | | EINECS: | | | Product Categories: | | | Mol File: | 1617-18-1.mol |  |
| | ETHYL 3-BUTENOATE Chemical Properties |
| | ETHYL 3-BUTENOATE Usage And Synthesis |
| Synthesis Reference(s) | Journal of the American Chemical Society, 86, p. 4350, 1964 DOI: 10.1021/ja01074a023
The Journal of Organic Chemistry, 49, p. 1341, 1984 DOI: 10.1021/jo00182a005 | | Synthesis | The synthesis of ETHYL 3-BUTENOATE is as follows:
step one: At room temperature,to a three-necked flask was added 600 parts of toluene,150 parts of triethylamine, 110 parts of ethanol,100 parts of crotonyl chloride were charged in a constant pressure separatory funnel, under electric stirring, toluene.The mixture of triethylamine and ethanol is mixed well, while heating the mixture to 55 °C, then through the constant pressure funnel control crotonyl chloride uniform dropping 1h, reaction overnight, gas chromatography to detect the progress of the reaction, record the reaction time;step two: The reaction is over. The reaction solution is cooled, the liquid is washed twice with water, dried over anhydrous magnesium sulfate, filtering, removing toluene solvent by rotary evaporation, 3-butenoic acid hexyl ester to give a crude product.
step three: The crude 3-butenyl caproate obtained in step two is in a ratio by weight of crude product: silica gel = 3-4: 1 with 120 mesh silica gel dry packing method, then the volume ratio of petroleum ether - ethyl acetate gradient elution, the eluate obtained by eluting with petroleum ether-ethyl acetate in a volume ratio of 200: 1 was recovered, rotary evaporation of petroleum ether - ethyl acetate. The product, hexyl 3-butenoate, weight and calculate yield.
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| | ETHYL 3-BUTENOATE Preparation Products And Raw materials |
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