ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Methyl ester compound Methyl 6-bromo-2-naphthoate

Methyl 6-bromo-2-naphthoate

Methyl 6-bromo-2-naphthoate Basic information
Product Name:Methyl 6-bromo-2-naphthoate
Synonyms:6-Bromo-2-Naphtoic Acid Methyl Ester;2-Bromo-6-naphthoic acid methylester;6-BROMO-2-NAPHTHALENECARBOXYLIC ACID METHYL ESTER;6-BROMO-2-NAPHTHOIC ACID METHYL ESTER;METHYL 6-BROMO-2-NAPHTHALENECARBOXYLATE;METHYL 6-BROMO-2-NAPHTHOATE;2-Naphthoic acid, 6-bromo, methyl ester;Methyl-6-bromo-2-naphtoate
CAS:33626-98-1
MF:C12H9BrO2
MW:265.1
EINECS:608-896-0
Product Categories:Naphthalene series;Building Blocks;C12 to C63;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Aromatic Esters;Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts;Intermediates of Adapalene;C12 to C63;Carbonyl Compounds;Esters;API;Others chemical reagents;blocks;Bromides;Carboxes;ADAPALENE
Mol File:33626-98-1.mol
Methyl 6-bromo-2-naphthoate Structure
Methyl 6-bromo-2-naphthoate Chemical Properties
Melting point 123-126 °C (lit.)
Boiling point 357.0±15.0 °C(Predicted)
density 1.492±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), DMSO (Slightly)
form Crystalline Powder
color Off-white to cream or light brown
BRN 2578943
InChIKeyJEUBRLPXJZOGPX-UHFFFAOYSA-N
CAS DataBase Reference33626-98-1(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 20/21/22-34
Safety Statements 24/25-45-36/37/39-27-26
WGK Germany 3
HS Code 29163990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Methyl 6-bromo-2-naphthoate Usage And Synthesis
Chemical PropertiesPale yellow or light brown powder
UsesMethyl 6-Bromo-2-napthoate is used in the synthesis of Adapalene, a retinoid specific for RARβ and RARγ receptors.
UsesMethyl 6-Bromo-2-napthoate (Adapalene USP Related Compound A) is used in the synthesis of Adapalene, a retinoid specific for RARβ and RARγ receptors.
UsesMethyl 6-bromo-2-naphthoate may be used to synthesize:
  • 6-vinyl-2-naphthalencarbaldehyde
  • methyl 6-(3-tert-butyl-4-methoxyphenyl)-2-naphthoate
  • methyl 6-[3-tert-butyl-4-[(tert-butyldiethylsilyl)oxy]-phenyl]-2-naphthoate
  • methyl 6-[3-(1-adamantyl)-4-[(tert-butyldimethylsilyl)-oxy]phenyl]-2-naphthoate
  • methyl 6-[3-(1-adamantyl)-4-[[(2,3-dimethyl-1,3-dioxolan-4-yl)methylloxy]phenyl]-2-naphthoate
  • 2-bromo-6-(bromomethyl)naphthalene
General DescriptionMethyl 6-bromo-2-naphthoate undergoes aromatic Finkelstein reaction followed by hydrolysis to afford 6-iodo-2-naphthoic acid.
Methyl 6-bromo-2-naphthoate Preparation Products And Raw materials
Preparation Products2,2'-Bis-(1-adaMantyl)-4,4'-diMethoxybiphenyl-->2-Acetyl-6-bromonaphthalene-->methyl 1-(6-bromonaphthalen-2-yl)cyclopropane-1-carboxylate-->6-BROMO-2-NAPHTHOHYDRAZIDE
Hydroxy Adapalene 1-Adamantanol 1-(5-Bromo-2-methoxy-phenyl)adamantane ETHYL 6-BROMO-1-HYDROXY-2-NAPHTHOATE 2-Naphthoic acid 6-Bromo-2-naphthoic acid METHYL 2-NAPHTHOATE AKOS 92331 AKOS 92252 6-Bromo-2-naphthoic acid methyl ester (Methyl 6-bromo-2-naphthoate) methyl 5-bromo-1-naphthoate Methyl 6-bromo-2-naphthoate METHYL 6-BROMO-2-NAPHTHOATE [307.1.7] 6-BROMO-2-CARBONAPHTHOXYCHOLINE IODIDE AKOS 92265 METHYL 5-BROMO-2-NAPHTHOATE Methyl 4-bromo-1-naphthoate,Methyl 4-bromo-1-naphthoate 98% AKOS 92241
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